(R)-2-[1-(2,6-Dichloro-3,4,5-trimeth­oxy­benzo­yl)pyrrolidin-2-yl]-4,4,5,5-tetra­methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide

In the title compound, C(21)H(28)Cl(2)N(3)O(6), the nitronyl nitroxide ring displays a half-chair conformation, whereas the pyrrolidine ring has an envelope conformation. These two rings are twisted to each other with N—C—C—N torsion angles around the connecting C—C bond of 48.9 (6) and −127.0 (5)°....

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Detalles Bibliográficos
Autores principales: Wang, Hai-Bo, Xiang, Zhuo, Jing, Lin-Lin, Tian, Min, Sun, Xiao-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099877/
https://www.ncbi.nlm.nih.gov/pubmed/21754243
http://dx.doi.org/10.1107/S1600536811010270
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author Wang, Hai-Bo
Xiang, Zhuo
Jing, Lin-Lin
Tian, Min
Sun, Xiao-Li
author_facet Wang, Hai-Bo
Xiang, Zhuo
Jing, Lin-Lin
Tian, Min
Sun, Xiao-Li
author_sort Wang, Hai-Bo
collection PubMed
description In the title compound, C(21)H(28)Cl(2)N(3)O(6), the nitronyl nitroxide ring displays a half-chair conformation, whereas the pyrrolidine ring has an envelope conformation. These two rings are twisted to each other with N—C—C—N torsion angles around the connecting C—C bond of 48.9 (6) and −127.0 (5)°. The benzene ring is nearly perpendicular to the pyrrolidine ring, with torsion angles around the connecting C—C bond of 86.3 (6) and −97.7 (6)°. The crystal structure is stabilized by C—H⋯O and C—H⋯π hydrogen bonds, which build up a three-dimensional network.
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spelling pubmed-30998772011-07-13 (R)-2-[1-(2,6-Dichloro-3,4,5-trimeth­oxy­benzo­yl)pyrrolidin-2-yl]-4,4,5,5-tetra­methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide Wang, Hai-Bo Xiang, Zhuo Jing, Lin-Lin Tian, Min Sun, Xiao-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(28)Cl(2)N(3)O(6), the nitronyl nitroxide ring displays a half-chair conformation, whereas the pyrrolidine ring has an envelope conformation. These two rings are twisted to each other with N—C—C—N torsion angles around the connecting C—C bond of 48.9 (6) and −127.0 (5)°. The benzene ring is nearly perpendicular to the pyrrolidine ring, with torsion angles around the connecting C—C bond of 86.3 (6) and −97.7 (6)°. The crystal structure is stabilized by C—H⋯O and C—H⋯π hydrogen bonds, which build up a three-dimensional network. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3099877/ /pubmed/21754243 http://dx.doi.org/10.1107/S1600536811010270 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Hai-Bo
Xiang, Zhuo
Jing, Lin-Lin
Tian, Min
Sun, Xiao-Li
(R)-2-[1-(2,6-Dichloro-3,4,5-trimeth­oxy­benzo­yl)pyrrolidin-2-yl]-4,4,5,5-tetra­methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide
title (R)-2-[1-(2,6-Dichloro-3,4,5-trimeth­oxy­benzo­yl)pyrrolidin-2-yl]-4,4,5,5-tetra­methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide
title_full (R)-2-[1-(2,6-Dichloro-3,4,5-trimeth­oxy­benzo­yl)pyrrolidin-2-yl]-4,4,5,5-tetra­methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide
title_fullStr (R)-2-[1-(2,6-Dichloro-3,4,5-trimeth­oxy­benzo­yl)pyrrolidin-2-yl]-4,4,5,5-tetra­methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide
title_full_unstemmed (R)-2-[1-(2,6-Dichloro-3,4,5-trimeth­oxy­benzo­yl)pyrrolidin-2-yl]-4,4,5,5-tetra­methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide
title_short (R)-2-[1-(2,6-Dichloro-3,4,5-trimeth­oxy­benzo­yl)pyrrolidin-2-yl]-4,4,5,5-tetra­methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide
title_sort (r)-2-[1-(2,6-dichloro-3,4,5-trimeth­oxy­benzo­yl)pyrrolidin-2-yl]-4,4,5,5-tetra­methyl-4,5-dihydro-1h-imidazole-1-oxyl 3-oxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099877/
https://www.ncbi.nlm.nih.gov/pubmed/21754243
http://dx.doi.org/10.1107/S1600536811010270
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