(4,5-Diaza­fluoren-9-one-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)

In the title compound, [Hg(NCS)(2)(C(11)H(6)N(2)O)], the Hg(II) atom, lying on a twofold rotation axis, is four-coordinated in a distorted tetra­hedral geometry by an N,N′-bidentate diaza­fluoren-9-one ligand and two thio­cyanate anions. In the crystal, inter­molecular C—H⋯N and C—H⋯O hydrogen bonds...

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Detalles Bibliográficos
Autores principales: Notash, Behrouz, Safari, Nasser, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099883/
https://www.ncbi.nlm.nih.gov/pubmed/21753948
http://dx.doi.org/10.1107/S1600536811008142
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author Notash, Behrouz
Safari, Nasser
Amani, Vahid
author_facet Notash, Behrouz
Safari, Nasser
Amani, Vahid
author_sort Notash, Behrouz
collection PubMed
description In the title compound, [Hg(NCS)(2)(C(11)H(6)N(2)O)], the Hg(II) atom, lying on a twofold rotation axis, is four-coordinated in a distorted tetra­hedral geometry by an N,N′-bidentate diaza­fluoren-9-one ligand and two thio­cyanate anions. In the crystal, inter­molecular C—H⋯N and C—H⋯O hydrogen bonds are effective in the stabilization of the structure.
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spelling pubmed-30998832011-07-13 (4,5-Diaza­fluoren-9-one-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II) Notash, Behrouz Safari, Nasser Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Hg(NCS)(2)(C(11)H(6)N(2)O)], the Hg(II) atom, lying on a twofold rotation axis, is four-coordinated in a distorted tetra­hedral geometry by an N,N′-bidentate diaza­fluoren-9-one ligand and two thio­cyanate anions. In the crystal, inter­molecular C—H⋯N and C—H⋯O hydrogen bonds are effective in the stabilization of the structure. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3099883/ /pubmed/21753948 http://dx.doi.org/10.1107/S1600536811008142 Text en © Notash et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Notash, Behrouz
Safari, Nasser
Amani, Vahid
(4,5-Diaza­fluoren-9-one-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)
title (4,5-Diaza­fluoren-9-one-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)
title_full (4,5-Diaza­fluoren-9-one-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)
title_fullStr (4,5-Diaza­fluoren-9-one-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)
title_full_unstemmed (4,5-Diaza­fluoren-9-one-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)
title_short (4,5-Diaza­fluoren-9-one-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)
title_sort (4,5-diaza­fluoren-9-one-κ(2) n,n′)bis­(thio­cyanato-κs)mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099883/
https://www.ncbi.nlm.nih.gov/pubmed/21753948
http://dx.doi.org/10.1107/S1600536811008142
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AT amanivahid 45diazafluoren9onek2nnbisthiocyanatoksmercuryii

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