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(E)-6-Bromo-3-{2-[2-(4-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one

In the title compound, C(19)H(11)N(3)O(2)SClBr, the chromene ring system and the thia­zole ring are each approximately planar, with maximum deviations of 0.033 (3) Å and 0.006 (3) Å, respectively. The mol­ecule adopts an E configuration about the central C=N double bond. The central thia­zole ring m...

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Autores principales: Arshad, Afsheen, Osman, Hasnah, Lam, Chan Kit, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099884/
https://www.ncbi.nlm.nih.gov/pubmed/21754027
http://dx.doi.org/10.1107/S1600536811011172
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author Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Arshad, Afsheen
collection PubMed
description In the title compound, C(19)H(11)N(3)O(2)SClBr, the chromene ring system and the thia­zole ring are each approximately planar, with maximum deviations of 0.033 (3) Å and 0.006 (3) Å, respectively. The mol­ecule adopts an E configuration about the central C=N double bond. The central thia­zole ring makes dihedral angles of 9.06 (14)° and 12.07 (11)° with the chloro-substituted phenyl ring and the chromene ring, respectively. The mol­ecular structure features a short C—H⋯O contact, which generates an S(6) ring motif. The crystal structure is stabilized by inter­molecular N—H⋯O hydrogen bonds, which link the mol­ecules into chains along the b axis. π–π stacking inter­actions [centroid-centroid distance = 3.4813 (15) Å] are also present.
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spelling pubmed-30998842011-07-13 (E)-6-Bromo-3-{2-[2-(4-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(11)N(3)O(2)SClBr, the chromene ring system and the thia­zole ring are each approximately planar, with maximum deviations of 0.033 (3) Å and 0.006 (3) Å, respectively. The mol­ecule adopts an E configuration about the central C=N double bond. The central thia­zole ring makes dihedral angles of 9.06 (14)° and 12.07 (11)° with the chloro-substituted phenyl ring and the chromene ring, respectively. The mol­ecular structure features a short C—H⋯O contact, which generates an S(6) ring motif. The crystal structure is stabilized by inter­molecular N—H⋯O hydrogen bonds, which link the mol­ecules into chains along the b axis. π–π stacking inter­actions [centroid-centroid distance = 3.4813 (15) Å] are also present. International Union of Crystallography 2011-03-31 /pmc/articles/PMC3099884/ /pubmed/21754027 http://dx.doi.org/10.1107/S1600536811011172 Text en © Arshad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Hemamalini, Madhukar
Fun, Hoong-Kun
(E)-6-Bromo-3-{2-[2-(4-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one
title (E)-6-Bromo-3-{2-[2-(4-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one
title_full (E)-6-Bromo-3-{2-[2-(4-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one
title_fullStr (E)-6-Bromo-3-{2-[2-(4-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one
title_full_unstemmed (E)-6-Bromo-3-{2-[2-(4-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one
title_short (E)-6-Bromo-3-{2-[2-(4-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one
title_sort (e)-6-bromo-3-{2-[2-(4-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2h-chromen-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099884/
https://www.ncbi.nlm.nih.gov/pubmed/21754027
http://dx.doi.org/10.1107/S1600536811011172
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