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4,4′-Dibromo-2,2′-{[(3aS,7aS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl]bis(methylidene)}diphenol
The cyclohexane ring in the title compound, C(21)H(24)Br(2)N(2)O(2), adopts a chair conformation and the five-membered ring to which it is fused has a twisted envelope conformation. The asymmetric unit contains one half-molecule, which is related to the other half by a twofold rotation axis. The t...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099886/ https://www.ncbi.nlm.nih.gov/pubmed/21754050 http://dx.doi.org/10.1107/S1600536811006489 |
| _version_ | 1782204108221972480 |
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| author | Rivera, Augusto Quiroga, Diego Ríos-Motta, Jaime Dušek, Michal Fejfarová, Karla |
| author_facet | Rivera, Augusto Quiroga, Diego Ríos-Motta, Jaime Dušek, Michal Fejfarová, Karla |
| author_sort | Rivera, Augusto |
| collection | PubMed |
| description | The cyclohexane ring in the title compound, C(21)H(24)Br(2)N(2)O(2), adopts a chair conformation and the five-membered ring to which it is fused has a twisted envelope conformation. The asymmetric unit contains one half-molecule, which is related to the other half by a twofold rotation axis. The two N atoms of the five-membered ring are linked to the hydroxy groups by intramolecular O—H⋯N hydrogen bonds. In the crystal, intermolecular C—H⋯O and C—H⋯π interactions occur. |
| format | Text |
| id | pubmed-3099886 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30998862011-07-13 4,4′-Dibromo-2,2′-{[(3aS,7aS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl]bis(methylidene)}diphenol Rivera, Augusto Quiroga, Diego Ríos-Motta, Jaime Dušek, Michal Fejfarová, Karla Acta Crystallogr Sect E Struct Rep Online Organic Papers The cyclohexane ring in the title compound, C(21)H(24)Br(2)N(2)O(2), adopts a chair conformation and the five-membered ring to which it is fused has a twisted envelope conformation. The asymmetric unit contains one half-molecule, which is related to the other half by a twofold rotation axis. The two N atoms of the five-membered ring are linked to the hydroxy groups by intramolecular O—H⋯N hydrogen bonds. In the crystal, intermolecular C—H⋯O and C—H⋯π interactions occur. International Union of Crystallography 2011-03-02 /pmc/articles/PMC3099886/ /pubmed/21754050 http://dx.doi.org/10.1107/S1600536811006489 Text en © Rivera et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Rivera, Augusto Quiroga, Diego Ríos-Motta, Jaime Dušek, Michal Fejfarová, Karla 4,4′-Dibromo-2,2′-{[(3aS,7aS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl]bis(methylidene)}diphenol |
| title | 4,4′-Dibromo-2,2′-{[(3aS,7aS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl]bis(methylidene)}diphenol |
| title_full | 4,4′-Dibromo-2,2′-{[(3aS,7aS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl]bis(methylidene)}diphenol |
| title_fullStr | 4,4′-Dibromo-2,2′-{[(3aS,7aS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl]bis(methylidene)}diphenol |
| title_full_unstemmed | 4,4′-Dibromo-2,2′-{[(3aS,7aS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl]bis(methylidene)}diphenol |
| title_short | 4,4′-Dibromo-2,2′-{[(3aS,7aS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl]bis(methylidene)}diphenol |
| title_sort | 4,4′-dibromo-2,2′-{[(3as,7as)-2,3,3a,4,5,6,7,7a-octahydro-1h-1,3-benzimidazole-1,3-diyl]bis(methylidene)}diphenol |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099886/ https://www.ncbi.nlm.nih.gov/pubmed/21754050 http://dx.doi.org/10.1107/S1600536811006489 |
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