1-Cyclo­hexyl-3-{(E)-[1-(pyridin-2-yl)ethyl­idene]amino}­thio­urea

In the title thio­urea derivative, C(14)H(20)N(4)S, the non-ring non-H atoms are approximately planar, with an r.m.s. deviation of 0.0720 Å. The pyridine ring is twisted out of this plane and makes a dihedral angle of 16.85 (13)° with it. The mean plane passing through the cyclo­hexyl ring is almost...

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Autores principales: Salam, Md. Abdus, Affan, Md. Abu, Ahmad, Fasihuddin B., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099887/
https://www.ncbi.nlm.nih.gov/pubmed/21754220
http://dx.doi.org/10.1107/S1600536811009317
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author Salam, Md. Abdus
Affan, Md. Abu
Ahmad, Fasihuddin B.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Salam, Md. Abdus
Affan, Md. Abu
Ahmad, Fasihuddin B.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Salam, Md. Abdus
collection PubMed
description In the title thio­urea derivative, C(14)H(20)N(4)S, the non-ring non-H atoms are approximately planar, with an r.m.s. deviation of 0.0720 Å. The pyridine ring is twisted out of this plane and makes a dihedral angle of 16.85 (13)° with it. The mean plane passing through the cyclo­hexyl ring is almost normal to the central plane [dihedral angle = 69.23 (8)°]. An intra­molecular N—H⋯N(imine) hydrogen bond occurs. Centrosymmetric dimers are formed in the crystal structure via pairs of N—H⋯S hydrogen bonds, and these are connected into a supra­molecular chain along the a axis via C—H⋯π(pyrid­yl) inter­actions.
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spelling pubmed-30998872011-07-13 1-Cyclo­hexyl-3-{(E)-[1-(pyridin-2-yl)ethyl­idene]amino}­thio­urea Salam, Md. Abdus Affan, Md. Abu Ahmad, Fasihuddin B. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title thio­urea derivative, C(14)H(20)N(4)S, the non-ring non-H atoms are approximately planar, with an r.m.s. deviation of 0.0720 Å. The pyridine ring is twisted out of this plane and makes a dihedral angle of 16.85 (13)° with it. The mean plane passing through the cyclo­hexyl ring is almost normal to the central plane [dihedral angle = 69.23 (8)°]. An intra­molecular N—H⋯N(imine) hydrogen bond occurs. Centrosymmetric dimers are formed in the crystal structure via pairs of N—H⋯S hydrogen bonds, and these are connected into a supra­molecular chain along the a axis via C—H⋯π(pyrid­yl) inter­actions. International Union of Crystallography 2011-03-23 /pmc/articles/PMC3099887/ /pubmed/21754220 http://dx.doi.org/10.1107/S1600536811009317 Text en © Salam et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Salam, Md. Abdus
Affan, Md. Abu
Ahmad, Fasihuddin B.
Ng, Seik Weng
Tiekink, Edward R. T.
1-Cyclo­hexyl-3-{(E)-[1-(pyridin-2-yl)ethyl­idene]amino}­thio­urea
title 1-Cyclo­hexyl-3-{(E)-[1-(pyridin-2-yl)ethyl­idene]amino}­thio­urea
title_full 1-Cyclo­hexyl-3-{(E)-[1-(pyridin-2-yl)ethyl­idene]amino}­thio­urea
title_fullStr 1-Cyclo­hexyl-3-{(E)-[1-(pyridin-2-yl)ethyl­idene]amino}­thio­urea
title_full_unstemmed 1-Cyclo­hexyl-3-{(E)-[1-(pyridin-2-yl)ethyl­idene]amino}­thio­urea
title_short 1-Cyclo­hexyl-3-{(E)-[1-(pyridin-2-yl)ethyl­idene]amino}­thio­urea
title_sort 1-cyclo­hexyl-3-{(e)-[1-(pyridin-2-yl)ethyl­idene]amino}­thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099887/
https://www.ncbi.nlm.nih.gov/pubmed/21754220
http://dx.doi.org/10.1107/S1600536811009317
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