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Poly[[μ(2)-aqua-μ(3)-(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(4) N (3),O (4):O (4):O (5))-sodium] hemihydrate]
In the title compound, {[Na(C(8)H(9)N(2)O(4))(H(2)O)]·0.5H(2)O}(n), the Na(+) ion is coordinated by two bridging water molecules, one N atom and three O atoms from three 4-carboxy-2-propyl-1H-imidazole-5-carboxylate (H(2)pimdc) ligands. Adjacent Na(+) ions are linked alternately by two water O at...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099890/ https://www.ncbi.nlm.nih.gov/pubmed/21753940 http://dx.doi.org/10.1107/S1600536811007732 |
Sumario: | In the title compound, {[Na(C(8)H(9)N(2)O(4))(H(2)O)]·0.5H(2)O}(n), the Na(+) ion is coordinated by two bridging water molecules, one N atom and three O atoms from three 4-carboxy-2-propyl-1H-imidazole-5-carboxylate (H(2)pimdc) ligands. Adjacent Na(+) ions are linked alternately by two water O atoms and two carboxy O atoms into a chain along [001]. These chains are connected through the coordination of the carboxylate O atoms to the Na(+) ions, forming a three-dimensional structure. An intramolecular O—H⋯O hydrogen bond and intermolecular N—H⋯O and O—H⋯O hydrogen bonds are present in the crystal structure. |
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