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Poly[[μ(2)-aqua-μ(3)-(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(4) N (3),O (4):O (4):O (5))-sodium] hemihydrate]

In the title compound, {[Na(C(8)H(9)N(2)O(4))(H(2)O)]·0.5H(2)O}(n), the Na(+) ion is coordinated by two bridging water mol­ecules, one N atom and three O atoms from three 4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ate (H(2)pimdc) ligands. Adjacent Na(+) ions are linked alternately by two water O at...

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Autores principales: Huang, Zhong-Jing, Tang, Jin-Niu, Luo, Zhi-Rong, Wang, Dai-Yin, Wei, Huan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099890/
https://www.ncbi.nlm.nih.gov/pubmed/21753940
http://dx.doi.org/10.1107/S1600536811007732
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author Huang, Zhong-Jing
Tang, Jin-Niu
Luo, Zhi-Rong
Wang, Dai-Yin
Wei, Huan
author_facet Huang, Zhong-Jing
Tang, Jin-Niu
Luo, Zhi-Rong
Wang, Dai-Yin
Wei, Huan
author_sort Huang, Zhong-Jing
collection PubMed
description In the title compound, {[Na(C(8)H(9)N(2)O(4))(H(2)O)]·0.5H(2)O}(n), the Na(+) ion is coordinated by two bridging water mol­ecules, one N atom and three O atoms from three 4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ate (H(2)pimdc) ligands. Adjacent Na(+) ions are linked alternately by two water O atoms and two carb­oxy O atoms into a chain along [001]. These chains are connected through the coordination of the carboxyl­ate O atoms to the Na(+) ions, forming a three-dimensional structure. An intra­molecular O—H⋯O hydrogen bond and inter­molecular N—H⋯O and O—H⋯O hydrogen bonds are present in the crystal structure.
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spelling pubmed-30998902011-07-13 Poly[[μ(2)-aqua-μ(3)-(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(4) N (3),O (4):O (4):O (5))-sodium] hemihydrate] Huang, Zhong-Jing Tang, Jin-Niu Luo, Zhi-Rong Wang, Dai-Yin Wei, Huan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Na(C(8)H(9)N(2)O(4))(H(2)O)]·0.5H(2)O}(n), the Na(+) ion is coordinated by two bridging water mol­ecules, one N atom and three O atoms from three 4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ate (H(2)pimdc) ligands. Adjacent Na(+) ions are linked alternately by two water O atoms and two carb­oxy O atoms into a chain along [001]. These chains are connected through the coordination of the carboxyl­ate O atoms to the Na(+) ions, forming a three-dimensional structure. An intra­molecular O—H⋯O hydrogen bond and inter­molecular N—H⋯O and O—H⋯O hydrogen bonds are present in the crystal structure. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3099890/ /pubmed/21753940 http://dx.doi.org/10.1107/S1600536811007732 Text en © Huang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Zhong-Jing
Tang, Jin-Niu
Luo, Zhi-Rong
Wang, Dai-Yin
Wei, Huan
Poly[[μ(2)-aqua-μ(3)-(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(4) N (3),O (4):O (4):O (5))-sodium] hemihydrate]
title Poly[[μ(2)-aqua-μ(3)-(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(4) N (3),O (4):O (4):O (5))-sodium] hemihydrate]
title_full Poly[[μ(2)-aqua-μ(3)-(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(4) N (3),O (4):O (4):O (5))-sodium] hemihydrate]
title_fullStr Poly[[μ(2)-aqua-μ(3)-(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(4) N (3),O (4):O (4):O (5))-sodium] hemihydrate]
title_full_unstemmed Poly[[μ(2)-aqua-μ(3)-(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(4) N (3),O (4):O (4):O (5))-sodium] hemihydrate]
title_short Poly[[μ(2)-aqua-μ(3)-(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(4) N (3),O (4):O (4):O (5))-sodium] hemihydrate]
title_sort poly[[μ(2)-aqua-μ(3)-(4-carb­oxy-2-propyl-1h-imidazole-5-carboxyl­ato-κ(4) n (3),o (4):o (4):o (5))-sodium] hemihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099890/
https://www.ncbi.nlm.nih.gov/pubmed/21753940
http://dx.doi.org/10.1107/S1600536811007732
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