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Poly[[μ(2)-aqua-μ(3)-(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(4) N (3),O (4):O (4):O (5))-sodium] hemihydrate]
In the title compound, {[Na(C(8)H(9)N(2)O(4))(H(2)O)]·0.5H(2)O}(n), the Na(+) ion is coordinated by two bridging water molecules, one N atom and three O atoms from three 4-carboxy-2-propyl-1H-imidazole-5-carboxylate (H(2)pimdc) ligands. Adjacent Na(+) ions are linked alternately by two water O at...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099890/ https://www.ncbi.nlm.nih.gov/pubmed/21753940 http://dx.doi.org/10.1107/S1600536811007732 |
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author | Huang, Zhong-Jing Tang, Jin-Niu Luo, Zhi-Rong Wang, Dai-Yin Wei, Huan |
author_facet | Huang, Zhong-Jing Tang, Jin-Niu Luo, Zhi-Rong Wang, Dai-Yin Wei, Huan |
author_sort | Huang, Zhong-Jing |
collection | PubMed |
description | In the title compound, {[Na(C(8)H(9)N(2)O(4))(H(2)O)]·0.5H(2)O}(n), the Na(+) ion is coordinated by two bridging water molecules, one N atom and three O atoms from three 4-carboxy-2-propyl-1H-imidazole-5-carboxylate (H(2)pimdc) ligands. Adjacent Na(+) ions are linked alternately by two water O atoms and two carboxy O atoms into a chain along [001]. These chains are connected through the coordination of the carboxylate O atoms to the Na(+) ions, forming a three-dimensional structure. An intramolecular O—H⋯O hydrogen bond and intermolecular N—H⋯O and O—H⋯O hydrogen bonds are present in the crystal structure. |
format | Text |
id | pubmed-3099890 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30998902011-07-13 Poly[[μ(2)-aqua-μ(3)-(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(4) N (3),O (4):O (4):O (5))-sodium] hemihydrate] Huang, Zhong-Jing Tang, Jin-Niu Luo, Zhi-Rong Wang, Dai-Yin Wei, Huan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Na(C(8)H(9)N(2)O(4))(H(2)O)]·0.5H(2)O}(n), the Na(+) ion is coordinated by two bridging water molecules, one N atom and three O atoms from three 4-carboxy-2-propyl-1H-imidazole-5-carboxylate (H(2)pimdc) ligands. Adjacent Na(+) ions are linked alternately by two water O atoms and two carboxy O atoms into a chain along [001]. These chains are connected through the coordination of the carboxylate O atoms to the Na(+) ions, forming a three-dimensional structure. An intramolecular O—H⋯O hydrogen bond and intermolecular N—H⋯O and O—H⋯O hydrogen bonds are present in the crystal structure. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3099890/ /pubmed/21753940 http://dx.doi.org/10.1107/S1600536811007732 Text en © Huang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Huang, Zhong-Jing Tang, Jin-Niu Luo, Zhi-Rong Wang, Dai-Yin Wei, Huan Poly[[μ(2)-aqua-μ(3)-(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(4) N (3),O (4):O (4):O (5))-sodium] hemihydrate] |
title | Poly[[μ(2)-aqua-μ(3)-(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(4)
N
(3),O
(4):O
(4):O
(5))-sodium] hemihydrate] |
title_full | Poly[[μ(2)-aqua-μ(3)-(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(4)
N
(3),O
(4):O
(4):O
(5))-sodium] hemihydrate] |
title_fullStr | Poly[[μ(2)-aqua-μ(3)-(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(4)
N
(3),O
(4):O
(4):O
(5))-sodium] hemihydrate] |
title_full_unstemmed | Poly[[μ(2)-aqua-μ(3)-(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(4)
N
(3),O
(4):O
(4):O
(5))-sodium] hemihydrate] |
title_short | Poly[[μ(2)-aqua-μ(3)-(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(4)
N
(3),O
(4):O
(4):O
(5))-sodium] hemihydrate] |
title_sort | poly[[μ(2)-aqua-μ(3)-(4-carboxy-2-propyl-1h-imidazole-5-carboxylato-κ(4)
n
(3),o
(4):o
(4):o
(5))-sodium] hemihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099890/ https://www.ncbi.nlm.nih.gov/pubmed/21753940 http://dx.doi.org/10.1107/S1600536811007732 |
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