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Di-μ-glutarato-κ(4) O (1):O (5)-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)copper(II)]

In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(12)H(18)N(2))(2)(H(2)O)(2)], the Cu(II) atom displays a dis­torted square-pyramidal coordination environment with the basal plane occupied by two phenanthroline N atoms and two O atoms from different glutarate dianions while a...

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Autor principal: Zhou, Yong-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099891/
https://www.ncbi.nlm.nih.gov/pubmed/21753943
http://dx.doi.org/10.1107/S1600536811007938
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author Zhou, Yong-Hong
author_facet Zhou, Yong-Hong
author_sort Zhou, Yong-Hong
collection PubMed
description In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(12)H(18)N(2))(2)(H(2)O)(2)], the Cu(II) atom displays a dis­torted square-pyramidal coordination environment with the basal plane occupied by two phenanthroline N atoms and two O atoms from different glutarate dianions while a water mol­ecule is located at the apical position. Of the two water H atoms, one is engaged in an intra­molecular hydrogen bond with a free oxygen of the dianion whereas the second is engaged in an inter­molecular hydrogen bond, building a corrugated layer parallel to (100). These layers are further connected through π–π stacking inter­actions involving symmetry-related phenanthroline rings [centroid–centroid distance = 3.5599 (17) and 3.5617 (18) Å], building a three dimensionnal network. C—H⋯π inter­actions involving the phenanthroline ring system are also observed.
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spelling pubmed-30998912011-07-13 Di-μ-glutarato-κ(4) O (1):O (5)-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)copper(II)] Zhou, Yong-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(12)H(18)N(2))(2)(H(2)O)(2)], the Cu(II) atom displays a dis­torted square-pyramidal coordination environment with the basal plane occupied by two phenanthroline N atoms and two O atoms from different glutarate dianions while a water mol­ecule is located at the apical position. Of the two water H atoms, one is engaged in an intra­molecular hydrogen bond with a free oxygen of the dianion whereas the second is engaged in an inter­molecular hydrogen bond, building a corrugated layer parallel to (100). These layers are further connected through π–π stacking inter­actions involving symmetry-related phenanthroline rings [centroid–centroid distance = 3.5599 (17) and 3.5617 (18) Å], building a three dimensionnal network. C—H⋯π inter­actions involving the phenanthroline ring system are also observed. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3099891/ /pubmed/21753943 http://dx.doi.org/10.1107/S1600536811007938 Text en © Yong-Hong Zhou 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhou, Yong-Hong
Di-μ-glutarato-κ(4) O (1):O (5)-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)copper(II)]
title Di-μ-glutarato-κ(4) O (1):O (5)-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)copper(II)]
title_full Di-μ-glutarato-κ(4) O (1):O (5)-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)copper(II)]
title_fullStr Di-μ-glutarato-κ(4) O (1):O (5)-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)copper(II)]
title_full_unstemmed Di-μ-glutarato-κ(4) O (1):O (5)-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)copper(II)]
title_short Di-μ-glutarato-κ(4) O (1):O (5)-bis­[aqua­(1,10-phenanthroline-κ(2) N,N′)copper(II)]
title_sort di-μ-glutarato-κ(4) o (1):o (5)-bis­[aqua­(1,10-phenanthroline-κ(2) n,n′)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099891/
https://www.ncbi.nlm.nih.gov/pubmed/21753943
http://dx.doi.org/10.1107/S1600536811007938
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