1,3-Di-n-butyl­thio­urea

In the title compound, C(9)H(20)N(2)S, the n-butyl groups are in syn and anti positions in relation to the C=S bond. In the crystal, two mol­ecules are connected by two N—H⋯S=C hydrogen bonds into a centrosymmetric dimer. Another N—H⋯S=C hydrogen bond links the dimers, forming layers with a hydro­ph...

Descripción completa

Detalles Bibliográficos
Autores principales: Okuniewski, Andrzej, Dąbrowska, Agnieszka, Chojnacki, Jaroslaw
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099899/
https://www.ncbi.nlm.nih.gov/pubmed/21754195
http://dx.doi.org/10.1107/S1600536811009743
_version_ 1782204111260745728
author Okuniewski, Andrzej
Dąbrowska, Agnieszka
Chojnacki, Jaroslaw
author_facet Okuniewski, Andrzej
Dąbrowska, Agnieszka
Chojnacki, Jaroslaw
author_sort Okuniewski, Andrzej
collection PubMed
description In the title compound, C(9)H(20)N(2)S, the n-butyl groups are in syn and anti positions in relation to the C=S bond. In the crystal, two mol­ecules are connected by two N—H⋯S=C hydrogen bonds into a centrosymmetric dimer. Another N—H⋯S=C hydrogen bond links the dimers, forming layers with a hydro­philic inter­ior and a hydro­phobic exterior, which spread across the (100) plane. Inter­lacing of the external butyl groups combines these layers into a three-dimensional structure.
format Text
id pubmed-3099899
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30998992011-07-13 1,3-Di-n-butyl­thio­urea Okuniewski, Andrzej Dąbrowska, Agnieszka Chojnacki, Jaroslaw Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(20)N(2)S, the n-butyl groups are in syn and anti positions in relation to the C=S bond. In the crystal, two mol­ecules are connected by two N—H⋯S=C hydrogen bonds into a centrosymmetric dimer. Another N—H⋯S=C hydrogen bond links the dimers, forming layers with a hydro­philic inter­ior and a hydro­phobic exterior, which spread across the (100) plane. Inter­lacing of the external butyl groups combines these layers into a three-dimensional structure. International Union of Crystallography 2011-03-19 /pmc/articles/PMC3099899/ /pubmed/21754195 http://dx.doi.org/10.1107/S1600536811009743 Text en © Okuniewski et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Okuniewski, Andrzej
Dąbrowska, Agnieszka
Chojnacki, Jaroslaw
1,3-Di-n-butyl­thio­urea
title 1,3-Di-n-butyl­thio­urea
title_full 1,3-Di-n-butyl­thio­urea
title_fullStr 1,3-Di-n-butyl­thio­urea
title_full_unstemmed 1,3-Di-n-butyl­thio­urea
title_short 1,3-Di-n-butyl­thio­urea
title_sort 1,3-di-n-butyl­thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099899/
https://www.ncbi.nlm.nih.gov/pubmed/21754195
http://dx.doi.org/10.1107/S1600536811009743
work_keys_str_mv AT okuniewskiandrzej 13dinbutylthiourea
AT dabrowskaagnieszka 13dinbutylthiourea
AT chojnackijaroslaw 13dinbutylthiourea

Ejemplares similares