Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaqua­bis­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))zincate(II) dihydrate

In the title compound, (C(4)H(8)N(3)O)(2)[Zn(C(7)H(3)NO(4))(2)(H(2)O)(2)]·2H(2)O, the Zn(II) ion is six-coordinated in a distorted octa­hedral geometry by two pyridine-2,4-dicarboxyl­ate (pydc) ligands in the equatorial plane and two water mol­ecules in the axial positions. The pydc ligands act as b...

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Detalles Bibliográficos
Autores principales: Aghabozorg, Hossein, Jafarbak, Fatemeh, Mirzaei, Masoud, Notash, Behrouz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099900/
https://www.ncbi.nlm.nih.gov/pubmed/21753959
http://dx.doi.org/10.1107/S1600536811008452
Descripción
Sumario:In the title compound, (C(4)H(8)N(3)O)(2)[Zn(C(7)H(3)NO(4))(2)(H(2)O)(2)]·2H(2)O, the Zn(II) ion is six-coordinated in a distorted octa­hedral geometry by two pyridine-2,4-dicarboxyl­ate (pydc) ligands in the equatorial plane and two water mol­ecules in the axial positions. The pydc ligands act as bidentate chelating ligands through one carboxyl­ate O atom and the pyridine N atom. Inter­molecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds stabilize the crystal structure.

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