Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaqua­bis­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))zincate(II) dihydrate

In the title compound, (C(4)H(8)N(3)O)(2)[Zn(C(7)H(3)NO(4))(2)(H(2)O)(2)]·2H(2)O, the Zn(II) ion is six-coordinated in a distorted octa­hedral geometry by two pyridine-2,4-dicarboxyl­ate (pydc) ligands in the equatorial plane and two water mol­ecules in the axial positions. The pydc ligands act as b...

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Detalles Bibliográficos
Autores principales: Aghabozorg, Hossein, Jafarbak, Fatemeh, Mirzaei, Masoud, Notash, Behrouz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099900/
https://www.ncbi.nlm.nih.gov/pubmed/21753959
http://dx.doi.org/10.1107/S1600536811008452
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author Aghabozorg, Hossein
Jafarbak, Fatemeh
Mirzaei, Masoud
Notash, Behrouz
author_facet Aghabozorg, Hossein
Jafarbak, Fatemeh
Mirzaei, Masoud
Notash, Behrouz
author_sort Aghabozorg, Hossein
collection PubMed
description In the title compound, (C(4)H(8)N(3)O)(2)[Zn(C(7)H(3)NO(4))(2)(H(2)O)(2)]·2H(2)O, the Zn(II) ion is six-coordinated in a distorted octa­hedral geometry by two pyridine-2,4-dicarboxyl­ate (pydc) ligands in the equatorial plane and two water mol­ecules in the axial positions. The pydc ligands act as bidentate chelating ligands through one carboxyl­ate O atom and the pyridine N atom. Inter­molecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds stabilize the crystal structure.
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spelling pubmed-30999002011-07-13 Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaqua­bis­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))zincate(II) dihydrate Aghabozorg, Hossein Jafarbak, Fatemeh Mirzaei, Masoud Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(4)H(8)N(3)O)(2)[Zn(C(7)H(3)NO(4))(2)(H(2)O)(2)]·2H(2)O, the Zn(II) ion is six-coordinated in a distorted octa­hedral geometry by two pyridine-2,4-dicarboxyl­ate (pydc) ligands in the equatorial plane and two water mol­ecules in the axial positions. The pydc ligands act as bidentate chelating ligands through one carboxyl­ate O atom and the pyridine N atom. Inter­molecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds stabilize the crystal structure. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3099900/ /pubmed/21753959 http://dx.doi.org/10.1107/S1600536811008452 Text en © Aghabozorg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Aghabozorg, Hossein
Jafarbak, Fatemeh
Mirzaei, Masoud
Notash, Behrouz
Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaqua­bis­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))zincate(II) dihydrate
title Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaqua­bis­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))zincate(II) dihydrate
title_full Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaqua­bis­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))zincate(II) dihydrate
title_fullStr Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaqua­bis­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))zincate(II) dihydrate
title_full_unstemmed Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaqua­bis­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))zincate(II) dihydrate
title_short Bis(1-methyl-4-oxoimidazolidin-2-iminium) diaqua­bis­(pyridine-2,4-dicarboxyl­ato-κ(2) N,O (2))zincate(II) dihydrate
title_sort bis(1-methyl-4-oxoimidazolidin-2-iminium) diaqua­bis­(pyridine-2,4-dicarboxyl­ato-κ(2) n,o (2))zincate(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099900/
https://www.ncbi.nlm.nih.gov/pubmed/21753959
http://dx.doi.org/10.1107/S1600536811008452
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