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4-{[4-(3,5-Dimethoxybenzamido)phenyl]sulfanyl}-N-methylpyridine-2-carboxamide
There are two independent molecules in the asymmetric unit of the title compound, C(22)H(21)N(3)O(4)S. The central benzene ring makes dihedral angles of 74.28 (6) and 68.84 (6)° with the pyridine and 3,5-dimethoxyphenyl rings, respectively, in one molecule [86.66 (6) and 81.14 (6)° respectively,...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099903/ https://www.ncbi.nlm.nih.gov/pubmed/21754137 http://dx.doi.org/10.1107/S1600536811006490 |
Sumario: | There are two independent molecules in the asymmetric unit of the title compound, C(22)H(21)N(3)O(4)S. The central benzene ring makes dihedral angles of 74.28 (6) and 68.84 (6)° with the pyridine and 3,5-dimethoxyphenyl rings, respectively, in one molecule [86.66 (6) and 81.14 (6)° respectively, in the other]. Each of the molecules forms a centrosymmetric dimer with another molecule via pairs of intermolecular N—H⋯O hydrogen bonds. These hydrogen bonds connect the N—H groups and the O atoms of the carbonyl groups next to the 3,5-dimethoxyphenyl rings. Additional intermolecular N—H⋯O interactions link the dimers in the crystal structure. |
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