4-[(Dieth­oxy­phosphino­yl)meth­yl]benzoic acid

In the title compound, C(12)H(17)N(2)O(5)P, the phospho­nate group is almost orthogonal to both the ethyl groups, with a dihedral angle of 83.75 (11)°. In the crystal, mol­ecules are linked into centrosymmetric dimers via pairs of O—H⋯O hydrogen bonds with an R (2) (2)(20) graph-set motif. The cryst...

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Autores principales: Karthikeyan, S., Sethusankar, K., Rajeshwaran, Ganesan Gobi, Mohanakrishnan, Arasambattu K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099904/
https://www.ncbi.nlm.nih.gov/pubmed/21754115
http://dx.doi.org/10.1107/S1600536811008282
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author Karthikeyan, S.
Sethusankar, K.
Rajeshwaran, Ganesan Gobi
Mohanakrishnan, Arasambattu K.
author_facet Karthikeyan, S.
Sethusankar, K.
Rajeshwaran, Ganesan Gobi
Mohanakrishnan, Arasambattu K.
author_sort Karthikeyan, S.
collection PubMed
description In the title compound, C(12)H(17)N(2)O(5)P, the phospho­nate group is almost orthogonal to both the ethyl groups, with a dihedral angle of 83.75 (11)°. In the crystal, mol­ecules are linked into centrosymmetric dimers via pairs of O—H⋯O hydrogen bonds with an R (2) (2)(20) graph-set motif. The crystal structure is further consolidated by weak C—H⋯π inter­actions.
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spelling pubmed-30999042011-07-13 4-[(Dieth­oxy­phosphino­yl)meth­yl]benzoic acid Karthikeyan, S. Sethusankar, K. Rajeshwaran, Ganesan Gobi Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(17)N(2)O(5)P, the phospho­nate group is almost orthogonal to both the ethyl groups, with a dihedral angle of 83.75 (11)°. In the crystal, mol­ecules are linked into centrosymmetric dimers via pairs of O—H⋯O hydrogen bonds with an R (2) (2)(20) graph-set motif. The crystal structure is further consolidated by weak C—H⋯π inter­actions. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3099904/ /pubmed/21754115 http://dx.doi.org/10.1107/S1600536811008282 Text en © Karthikeyan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Karthikeyan, S.
Sethusankar, K.
Rajeshwaran, Ganesan Gobi
Mohanakrishnan, Arasambattu K.
4-[(Dieth­oxy­phosphino­yl)meth­yl]benzoic acid
title 4-[(Dieth­oxy­phosphino­yl)meth­yl]benzoic acid
title_full 4-[(Dieth­oxy­phosphino­yl)meth­yl]benzoic acid
title_fullStr 4-[(Dieth­oxy­phosphino­yl)meth­yl]benzoic acid
title_full_unstemmed 4-[(Dieth­oxy­phosphino­yl)meth­yl]benzoic acid
title_short 4-[(Dieth­oxy­phosphino­yl)meth­yl]benzoic acid
title_sort 4-[(dieth­oxy­phosphino­yl)meth­yl]benzoic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099904/
https://www.ncbi.nlm.nih.gov/pubmed/21754115
http://dx.doi.org/10.1107/S1600536811008282
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AT sethusankark 4diethoxyphosphinoylmethylbenzoicacid
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AT mohanakrishnanarasambattuk 4diethoxyphosphinoylmethylbenzoicacid

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