(3aR,6S,7aR)-7a-Bromo-2-[(4-methyl­phen­yl)sulfon­yl]-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole

In the title compound, C(15)H(16)BrNO(3)S, the boat form of the six-membered ring is almost symmetrical with respect to the ep­oxy bridge. The two five-membered rings generated by the ep­oxy bridge of the six-membered ring adopt envelope conformations, whereas the N-containing five-membered ring ado...

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Detalles Bibliográficos
Autores principales: Koşar, Başak, Demircan, Aydın, Arslan, Hakan, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099917/
https://www.ncbi.nlm.nih.gov/pubmed/21754251
http://dx.doi.org/10.1107/S1600536811010750
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author Koşar, Başak
Demircan, Aydın
Arslan, Hakan
Büyükgüngör, Orhan
author_facet Koşar, Başak
Demircan, Aydın
Arslan, Hakan
Büyükgüngör, Orhan
author_sort Koşar, Başak
collection PubMed
description In the title compound, C(15)H(16)BrNO(3)S, the boat form of the six-membered ring is almost symmetrical with respect to the ep­oxy bridge. The two five-membered rings generated by the ep­oxy bridge of the six-membered ring adopt envelope conformations, whereas the N-containing five-membered ring adopts a twisted conformation. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds.
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spelling pubmed-30999172011-07-13 (3aR,6S,7aR)-7a-Bromo-2-[(4-methyl­phen­yl)sulfon­yl]-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole Koşar, Başak Demircan, Aydın Arslan, Hakan Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(16)BrNO(3)S, the boat form of the six-membered ring is almost symmetrical with respect to the ep­oxy bridge. The two five-membered rings generated by the ep­oxy bridge of the six-membered ring adopt envelope conformations, whereas the N-containing five-membered ring adopts a twisted conformation. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds. International Union of Crystallography 2011-03-31 /pmc/articles/PMC3099917/ /pubmed/21754251 http://dx.doi.org/10.1107/S1600536811010750 Text en © Koşar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Koşar, Başak
Demircan, Aydın
Arslan, Hakan
Büyükgüngör, Orhan
(3aR,6S,7aR)-7a-Bromo-2-[(4-methyl­phen­yl)sulfon­yl]-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
title (3aR,6S,7aR)-7a-Bromo-2-[(4-methyl­phen­yl)sulfon­yl]-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
title_full (3aR,6S,7aR)-7a-Bromo-2-[(4-methyl­phen­yl)sulfon­yl]-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
title_fullStr (3aR,6S,7aR)-7a-Bromo-2-[(4-methyl­phen­yl)sulfon­yl]-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
title_full_unstemmed (3aR,6S,7aR)-7a-Bromo-2-[(4-methyl­phen­yl)sulfon­yl]-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
title_short (3aR,6S,7aR)-7a-Bromo-2-[(4-methyl­phen­yl)sulfon­yl]-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
title_sort (3ar,6s,7ar)-7a-bromo-2-[(4-methyl­phen­yl)sulfon­yl]-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099917/
https://www.ncbi.nlm.nih.gov/pubmed/21754251
http://dx.doi.org/10.1107/S1600536811010750
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