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Poly[[triaqua(μ(3)-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]
In the title coordination polymer, {[Tm(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tm(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO(7) coordination geom...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099919/ https://www.ncbi.nlm.nih.gov/pubmed/21753941 http://dx.doi.org/10.1107/S1600536811007628 |
Sumario: | In the title coordination polymer, {[Tm(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tm(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO(7) coordination geometry. The anions bridge adjacent Tm(III) ions into double chains. Adjacent chains are further connected into sheets. O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water molecules generate a three-dimensional supramolecular framework. |
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