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Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(III)] monohydrate]

In the title coordination polymer, {[Tm(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tm(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate trianion, two monodentate anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic TmNO(7) coordination geom...

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Detalles Bibliográficos
Autores principales: Gao, Zhu-Qing, Lv, Dong-Yu, Gu, Jin-Zhong, Li, Hong-Jin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099919/
https://www.ncbi.nlm.nih.gov/pubmed/21753941
http://dx.doi.org/10.1107/S1600536811007628
Descripción
Sumario:In the title coordination polymer, {[Tm(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tm(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate trianion, two monodentate anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic TmNO(7) coordination geometry. The anions bridge adjacent Tm(III) ions into double chains. Adjacent chains are further connected into sheets. O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water mol­ecules generate a three-dimensional supra­molecular framework.