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Poly[[triaqua(μ(3)-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]
In the title coordination polymer, {[Tm(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tm(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO(7) coordination geom...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099919/ https://www.ncbi.nlm.nih.gov/pubmed/21753941 http://dx.doi.org/10.1107/S1600536811007628 |
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author | Gao, Zhu-Qing Lv, Dong-Yu Gu, Jin-Zhong Li, Hong-Jin |
author_facet | Gao, Zhu-Qing Lv, Dong-Yu Gu, Jin-Zhong Li, Hong-Jin |
author_sort | Gao, Zhu-Qing |
collection | PubMed |
description | In the title coordination polymer, {[Tm(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tm(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO(7) coordination geometry. The anions bridge adjacent Tm(III) ions into double chains. Adjacent chains are further connected into sheets. O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water molecules generate a three-dimensional supramolecular framework. |
format | Text |
id | pubmed-3099919 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30999192011-07-13 Poly[[triaqua(μ(3)-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate] Gao, Zhu-Qing Lv, Dong-Yu Gu, Jin-Zhong Li, Hong-Jin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Tm(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tm(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO(7) coordination geometry. The anions bridge adjacent Tm(III) ions into double chains. Adjacent chains are further connected into sheets. O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water molecules generate a three-dimensional supramolecular framework. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3099919/ /pubmed/21753941 http://dx.doi.org/10.1107/S1600536811007628 Text en © Gao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Zhu-Qing Lv, Dong-Yu Gu, Jin-Zhong Li, Hong-Jin Poly[[triaqua(μ(3)-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate] |
title | Poly[[triaqua(μ(3)-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate] |
title_full | Poly[[triaqua(μ(3)-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate] |
title_fullStr | Poly[[triaqua(μ(3)-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate] |
title_full_unstemmed | Poly[[triaqua(μ(3)-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate] |
title_short | Poly[[triaqua(μ(3)-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate] |
title_sort | poly[[triaqua(μ(3)-4-oxidopyridine-2,6-dicarboxylato)thulium(iii)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099919/ https://www.ncbi.nlm.nih.gov/pubmed/21753941 http://dx.doi.org/10.1107/S1600536811007628 |
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