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Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(III)] monohydrate]

In the title coordination polymer, {[Tm(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tm(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate trianion, two monodentate anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic TmNO(7) coordination geom...

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Detalles Bibliográficos
Autores principales: Gao, Zhu-Qing, Lv, Dong-Yu, Gu, Jin-Zhong, Li, Hong-Jin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099919/
https://www.ncbi.nlm.nih.gov/pubmed/21753941
http://dx.doi.org/10.1107/S1600536811007628
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author Gao, Zhu-Qing
Lv, Dong-Yu
Gu, Jin-Zhong
Li, Hong-Jin
author_facet Gao, Zhu-Qing
Lv, Dong-Yu
Gu, Jin-Zhong
Li, Hong-Jin
author_sort Gao, Zhu-Qing
collection PubMed
description In the title coordination polymer, {[Tm(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tm(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate trianion, two monodentate anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic TmNO(7) coordination geometry. The anions bridge adjacent Tm(III) ions into double chains. Adjacent chains are further connected into sheets. O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water mol­ecules generate a three-dimensional supra­molecular framework.
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spelling pubmed-30999192011-07-13 Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(III)] monohydrate] Gao, Zhu-Qing Lv, Dong-Yu Gu, Jin-Zhong Li, Hong-Jin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Tm(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Tm(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl­ate trianion, two monodentate anions and three water mol­ecules, forming a distorted bicapped trigonal–prismatic TmNO(7) coordination geometry. The anions bridge adjacent Tm(III) ions into double chains. Adjacent chains are further connected into sheets. O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water mol­ecules generate a three-dimensional supra­molecular framework. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3099919/ /pubmed/21753941 http://dx.doi.org/10.1107/S1600536811007628 Text en © Gao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Zhu-Qing
Lv, Dong-Yu
Gu, Jin-Zhong
Li, Hong-Jin
Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(III)] monohydrate]
title Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(III)] monohydrate]
title_full Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(III)] monohydrate]
title_fullStr Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(III)] monohydrate]
title_full_unstemmed Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(III)] monohydrate]
title_short Poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(III)] monohydrate]
title_sort poly[[triaqua­(μ(3)-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(iii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099919/
https://www.ncbi.nlm.nih.gov/pubmed/21753941
http://dx.doi.org/10.1107/S1600536811007628
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