Cu(2)ZnSiS(4)

Single crystals of Cu(2)ZnSiS(4), dicopper(I) zinc silicon tetrasulfide, have been prepared via high-temperature solid-state synthesis. Cu(2)ZnSiS(4) was found to have the wurtz-stannite structure type, like that of Li(2)CdGeS(4), Li(2)CdSnS(4), and Cu(2)CdSiS(4). Each sulfur anion is tetra­hedrally...

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Detalles Bibliográficos
Autores principales: Rosmus, Kimberly A., Aitken, Jennifer A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099923/
https://www.ncbi.nlm.nih.gov/pubmed/21753925
http://dx.doi.org/10.1107/S1600536811008889
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author Rosmus, Kimberly A.
Aitken, Jennifer A.
author_facet Rosmus, Kimberly A.
Aitken, Jennifer A.
author_sort Rosmus, Kimberly A.
collection PubMed
description Single crystals of Cu(2)ZnSiS(4), dicopper(I) zinc silicon tetrasulfide, have been prepared via high-temperature solid-state synthesis. Cu(2)ZnSiS(4) was found to have the wurtz-stannite structure type, like that of Li(2)CdGeS(4), Li(2)CdSnS(4), and Cu(2)CdSiS(4). Each sulfur anion is tetra­hedrally coordinated by two Cu cations, one Si cation, and one Zn cation, forming a three-dimensional honeycomb structure. When viewed along the c axis, the atoms are aligned in rows in which each cation alternates with the sulfur anions.
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spelling pubmed-30999232011-07-13 Cu(2)ZnSiS(4) Rosmus, Kimberly A. Aitken, Jennifer A. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of Cu(2)ZnSiS(4), dicopper(I) zinc silicon tetrasulfide, have been prepared via high-temperature solid-state synthesis. Cu(2)ZnSiS(4) was found to have the wurtz-stannite structure type, like that of Li(2)CdGeS(4), Li(2)CdSnS(4), and Cu(2)CdSiS(4). Each sulfur anion is tetra­hedrally coordinated by two Cu cations, one Si cation, and one Zn cation, forming a three-dimensional honeycomb structure. When viewed along the c axis, the atoms are aligned in rows in which each cation alternates with the sulfur anions. International Union of Crystallography 2011-03-15 /pmc/articles/PMC3099923/ /pubmed/21753925 http://dx.doi.org/10.1107/S1600536811008889 Text en © Rosmus and Aitken 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Rosmus, Kimberly A.
Aitken, Jennifer A.
Cu(2)ZnSiS(4)
title Cu(2)ZnSiS(4)
title_full Cu(2)ZnSiS(4)
title_fullStr Cu(2)ZnSiS(4)
title_full_unstemmed Cu(2)ZnSiS(4)
title_short Cu(2)ZnSiS(4)
title_sort cu(2)znsis(4)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099923/
https://www.ncbi.nlm.nih.gov/pubmed/21753925
http://dx.doi.org/10.1107/S1600536811008889
work_keys_str_mv AT rosmuskimberlya cu2znsis4
AT aitkenjennifera cu2znsis4

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