Dicarbonyl­dichloridobis(trimethyl­phosphane)iron(II)–carbonyl­dichlorido­tris(trimethyl­phosphane)iron(II)–tetra­hydro­furan (1/1/2)

The asymmetric unit of the title crystal, [FeCl(2)(C(3)H(9)P)(3)(CO)]·[FeCl(2)(C(3)H(9)P)(2)(CO)(2)]·2C(4)H(8)O, contains half mol­ecules of the two closely related Fe(II) complexes lying on mirror planes and a tetra­hydro­furan solvent mol­ecule, one C atom of which is disordered over two sets of s...

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Detalles Bibliográficos
Autores principales: Rath, Nigam P., Stouffer, Meghan, Janssen, Matthew K., Bleeke, John R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099925/
https://www.ncbi.nlm.nih.gov/pubmed/21753978
http://dx.doi.org/10.1107/S1600536811009305
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author Rath, Nigam P.
Stouffer, Meghan
Janssen, Matthew K.
Bleeke, John R.
author_facet Rath, Nigam P.
Stouffer, Meghan
Janssen, Matthew K.
Bleeke, John R.
author_sort Rath, Nigam P.
collection PubMed
description The asymmetric unit of the title crystal, [FeCl(2)(C(3)H(9)P)(3)(CO)]·[FeCl(2)(C(3)H(9)P)(2)(CO)(2)]·2C(4)H(8)O, contains half mol­ecules of the two closely related Fe(II) complexes lying on mirror planes and a tetra­hydro­furan solvent mol­ecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both Fe(II) complex mol­ecules, a distorted octa­hedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C—H⋯O inter­actions are observed in the crystal structure.
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spelling pubmed-30999252011-07-13 Dicarbonyl­dichloridobis(trimethyl­phosphane)iron(II)–carbonyl­dichlorido­tris(trimethyl­phosphane)iron(II)–tetra­hydro­furan (1/1/2) Rath, Nigam P. Stouffer, Meghan Janssen, Matthew K. Bleeke, John R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title crystal, [FeCl(2)(C(3)H(9)P)(3)(CO)]·[FeCl(2)(C(3)H(9)P)(2)(CO)(2)]·2C(4)H(8)O, contains half mol­ecules of the two closely related Fe(II) complexes lying on mirror planes and a tetra­hydro­furan solvent mol­ecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both Fe(II) complex mol­ecules, a distorted octa­hedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C—H⋯O inter­actions are observed in the crystal structure. International Union of Crystallography 2011-03-19 /pmc/articles/PMC3099925/ /pubmed/21753978 http://dx.doi.org/10.1107/S1600536811009305 Text en © Rath et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rath, Nigam P.
Stouffer, Meghan
Janssen, Matthew K.
Bleeke, John R.
Dicarbonyl­dichloridobis(trimethyl­phosphane)iron(II)–carbonyl­dichlorido­tris(trimethyl­phosphane)iron(II)–tetra­hydro­furan (1/1/2)
title Dicarbonyl­dichloridobis(trimethyl­phosphane)iron(II)–carbonyl­dichlorido­tris(trimethyl­phosphane)iron(II)–tetra­hydro­furan (1/1/2)
title_full Dicarbonyl­dichloridobis(trimethyl­phosphane)iron(II)–carbonyl­dichlorido­tris(trimethyl­phosphane)iron(II)–tetra­hydro­furan (1/1/2)
title_fullStr Dicarbonyl­dichloridobis(trimethyl­phosphane)iron(II)–carbonyl­dichlorido­tris(trimethyl­phosphane)iron(II)–tetra­hydro­furan (1/1/2)
title_full_unstemmed Dicarbonyl­dichloridobis(trimethyl­phosphane)iron(II)–carbonyl­dichlorido­tris(trimethyl­phosphane)iron(II)–tetra­hydro­furan (1/1/2)
title_short Dicarbonyl­dichloridobis(trimethyl­phosphane)iron(II)–carbonyl­dichlorido­tris(trimethyl­phosphane)iron(II)–tetra­hydro­furan (1/1/2)
title_sort dicarbonyl­dichloridobis(trimethyl­phosphane)iron(ii)–carbonyl­dichlorido­tris(trimethyl­phosphane)iron(ii)–tetra­hydro­furan (1/1/2)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099925/
https://www.ncbi.nlm.nih.gov/pubmed/21753978
http://dx.doi.org/10.1107/S1600536811009305
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AT janssenmatthewk dicarbonyldichloridobistrimethylphosphaneironiicarbonyldichloridotristrimethylphosphaneironiitetrahydrofuran112
AT bleekejohnr dicarbonyldichloridobistrimethylphosphaneironiicarbonyldichloridotristrimethylphosphaneironiitetrahydrofuran112

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