Tris(piperazine-1,4-diium) bis­[hexa­chloridoindate(III)] tetra­hydrate

The asymmetric unit of the title compound, (C(4)H(12)N(2))(3)[InCl(6)](2)·4H(2)O, consists of one and half independent piperazinium cations, an hexa­chloridoindate anion and two mol­ecules of water. The In(III) ion is six-coordinated and forms a quasi-regular octa­hedral arrangement. In the crystal,...

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Autores principales: Bouacida, Sofiane, Belhouas, Ratiba, Fantazi, Boubakeur, Boudaren, Chaouki, Roisnel, Thierry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099932/
https://www.ncbi.nlm.nih.gov/pubmed/21753936
http://dx.doi.org/10.1107/S1600536811007355
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author Bouacida, Sofiane
Belhouas, Ratiba
Fantazi, Boubakeur
Boudaren, Chaouki
Roisnel, Thierry
author_facet Bouacida, Sofiane
Belhouas, Ratiba
Fantazi, Boubakeur
Boudaren, Chaouki
Roisnel, Thierry
author_sort Bouacida, Sofiane
collection PubMed
description The asymmetric unit of the title compound, (C(4)H(12)N(2))(3)[InCl(6)](2)·4H(2)O, consists of one and half independent piperazinium cations, an hexa­chloridoindate anion and two mol­ecules of water. The In(III) ion is six-coordinated and forms a quasi-regular octa­hedral arrangement. In the crystal, alternating layers of cations and anions are arranged parallel to (10[Image: see text]) and are linked with the water mol­ecules via intra- and inter­molecular N—H⋯O, O—H⋯Cl, C—H⋯O and N—H⋯Cl hydrogen bonds, forming a complex three-dimensional network. Additional stabilization within the layers is provided by weak inter­molecular C—H⋯Cl inter­actions.
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spelling pubmed-30999322011-07-13 Tris(piperazine-1,4-diium) bis­[hexa­chloridoindate(III)] tetra­hydrate Bouacida, Sofiane Belhouas, Ratiba Fantazi, Boubakeur Boudaren, Chaouki Roisnel, Thierry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(4)H(12)N(2))(3)[InCl(6)](2)·4H(2)O, consists of one and half independent piperazinium cations, an hexa­chloridoindate anion and two mol­ecules of water. The In(III) ion is six-coordinated and forms a quasi-regular octa­hedral arrangement. In the crystal, alternating layers of cations and anions are arranged parallel to (10[Image: see text]) and are linked with the water mol­ecules via intra- and inter­molecular N—H⋯O, O—H⋯Cl, C—H⋯O and N—H⋯Cl hydrogen bonds, forming a complex three-dimensional network. Additional stabilization within the layers is provided by weak inter­molecular C—H⋯Cl inter­actions. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3099932/ /pubmed/21753936 http://dx.doi.org/10.1107/S1600536811007355 Text en © Bouacida et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bouacida, Sofiane
Belhouas, Ratiba
Fantazi, Boubakeur
Boudaren, Chaouki
Roisnel, Thierry
Tris(piperazine-1,4-diium) bis­[hexa­chloridoindate(III)] tetra­hydrate
title Tris(piperazine-1,4-diium) bis­[hexa­chloridoindate(III)] tetra­hydrate
title_full Tris(piperazine-1,4-diium) bis­[hexa­chloridoindate(III)] tetra­hydrate
title_fullStr Tris(piperazine-1,4-diium) bis­[hexa­chloridoindate(III)] tetra­hydrate
title_full_unstemmed Tris(piperazine-1,4-diium) bis­[hexa­chloridoindate(III)] tetra­hydrate
title_short Tris(piperazine-1,4-diium) bis­[hexa­chloridoindate(III)] tetra­hydrate
title_sort tris(piperazine-1,4-diium) bis­[hexa­chloridoindate(iii)] tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099932/
https://www.ncbi.nlm.nih.gov/pubmed/21753936
http://dx.doi.org/10.1107/S1600536811007355
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AT boudarenchaouki trispiperazine14diiumbishexachloridoindateiiitetrahydrate
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