1-(2,5-Dimethyl­phen­yl)piperazine-1,4-diium tetra­chloridozincate monohydrate

In the title compound, (C(12)H(20)N(2))[ZnCl(4)]·H(2)O, the two piperazine N atoms are protonated and the [ZnCl(4)](2−) anions adopt a slightly distorted tetra­hedral configuration. In the crystal, O—H⋯Cl hydrogen bonds link the tetra­chloridozincate anions and the water mol­ecules into corrugated i...

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Detalles Bibliográficos
Autores principales: Kefi, Riadh, Lefebvre, Frédéric, Zeller, Matthias, Ben Nasr, Cherif
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099933/
https://www.ncbi.nlm.nih.gov/pubmed/21753942
http://dx.doi.org/10.1107/S1600536811007562
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author Kefi, Riadh
Lefebvre, Frédéric
Zeller, Matthias
Ben Nasr, Cherif
author_facet Kefi, Riadh
Lefebvre, Frédéric
Zeller, Matthias
Ben Nasr, Cherif
author_sort Kefi, Riadh
collection PubMed
description In the title compound, (C(12)H(20)N(2))[ZnCl(4)]·H(2)O, the two piperazine N atoms are protonated and the [ZnCl(4)](2−) anions adopt a slightly distorted tetra­hedral configuration. In the crystal, O—H⋯Cl hydrogen bonds link the tetra­chloridozincate anions and the water mol­ecules into corrugated inorganic chains parallel to [010]. The crystal structure is stabilized by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds, with the N—H hydrogen bond originating from one of the two N atoms being trifurcated.
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spelling pubmed-30999332011-07-13 1-(2,5-Dimethyl­phen­yl)piperazine-1,4-diium tetra­chloridozincate monohydrate Kefi, Riadh Lefebvre, Frédéric Zeller, Matthias Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(12)H(20)N(2))[ZnCl(4)]·H(2)O, the two piperazine N atoms are protonated and the [ZnCl(4)](2−) anions adopt a slightly distorted tetra­hedral configuration. In the crystal, O—H⋯Cl hydrogen bonds link the tetra­chloridozincate anions and the water mol­ecules into corrugated inorganic chains parallel to [010]. The crystal structure is stabilized by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds, with the N—H hydrogen bond originating from one of the two N atoms being trifurcated. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3099933/ /pubmed/21753942 http://dx.doi.org/10.1107/S1600536811007562 Text en © Kefi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kefi, Riadh
Lefebvre, Frédéric
Zeller, Matthias
Ben Nasr, Cherif
1-(2,5-Dimethyl­phen­yl)piperazine-1,4-diium tetra­chloridozincate monohydrate
title 1-(2,5-Dimethyl­phen­yl)piperazine-1,4-diium tetra­chloridozincate monohydrate
title_full 1-(2,5-Dimethyl­phen­yl)piperazine-1,4-diium tetra­chloridozincate monohydrate
title_fullStr 1-(2,5-Dimethyl­phen­yl)piperazine-1,4-diium tetra­chloridozincate monohydrate
title_full_unstemmed 1-(2,5-Dimethyl­phen­yl)piperazine-1,4-diium tetra­chloridozincate monohydrate
title_short 1-(2,5-Dimethyl­phen­yl)piperazine-1,4-diium tetra­chloridozincate monohydrate
title_sort 1-(2,5-dimethyl­phen­yl)piperazine-1,4-diium tetra­chloridozincate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099933/
https://www.ncbi.nlm.nih.gov/pubmed/21753942
http://dx.doi.org/10.1107/S1600536811007562
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AT bennasrcherif 125dimethylphenylpiperazine14diiumtetrachloridozincatemonohydrate

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