Bis(acetato-κ(2) O,O′)[2,6-bis­(1H-pyrazol-3-yl-κN (2))pyridine-κN]manganese(II)

In the title complex, [Mn(CH(3)CO(2))(2)(C(11)H(9)N(5))], the Mn(II) atom is coordinated by the pyridine N atom and two pyrazole N atoms from a 2,6-bis­(pyrazol-3-yl)pyridine ligand and four O atoms from two bidentate acetate ligands. The complex mol­ecules are linked by inter­molecular N—H⋯O hydrog...

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Detalles Bibliográficos
Autores principales: Yu, Fan, Li, Bao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099944/
https://www.ncbi.nlm.nih.gov/pubmed/21754009
http://dx.doi.org/10.1107/S1600536811010506
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author Yu, Fan
Li, Bao
author_facet Yu, Fan
Li, Bao
author_sort Yu, Fan
collection PubMed
description In the title complex, [Mn(CH(3)CO(2))(2)(C(11)H(9)N(5))], the Mn(II) atom is coordinated by the pyridine N atom and two pyrazole N atoms from a 2,6-bis­(pyrazol-3-yl)pyridine ligand and four O atoms from two bidentate acetate ligands. The complex mol­ecules are linked by inter­molecular N—H⋯O hydrogen bonds into a chain along [010]. π–π inter­actions between the pyridine rings and between the pyrazole rings [centroid–centroid distances = 3.772 (2) and 3.546 (2) Å] connect the chains.
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spelling pubmed-30999442011-07-13 Bis(acetato-κ(2) O,O′)[2,6-bis­(1H-pyrazol-3-yl-κN (2))pyridine-κN]manganese(II) Yu, Fan Li, Bao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(CH(3)CO(2))(2)(C(11)H(9)N(5))], the Mn(II) atom is coordinated by the pyridine N atom and two pyrazole N atoms from a 2,6-bis­(pyrazol-3-yl)pyridine ligand and four O atoms from two bidentate acetate ligands. The complex mol­ecules are linked by inter­molecular N—H⋯O hydrogen bonds into a chain along [010]. π–π inter­actions between the pyridine rings and between the pyrazole rings [centroid–centroid distances = 3.772 (2) and 3.546 (2) Å] connect the chains. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3099944/ /pubmed/21754009 http://dx.doi.org/10.1107/S1600536811010506 Text en © Yu and Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Fan
Li, Bao
Bis(acetato-κ(2) O,O′)[2,6-bis­(1H-pyrazol-3-yl-κN (2))pyridine-κN]manganese(II)
title Bis(acetato-κ(2) O,O′)[2,6-bis­(1H-pyrazol-3-yl-κN (2))pyridine-κN]manganese(II)
title_full Bis(acetato-κ(2) O,O′)[2,6-bis­(1H-pyrazol-3-yl-κN (2))pyridine-κN]manganese(II)
title_fullStr Bis(acetato-κ(2) O,O′)[2,6-bis­(1H-pyrazol-3-yl-κN (2))pyridine-κN]manganese(II)
title_full_unstemmed Bis(acetato-κ(2) O,O′)[2,6-bis­(1H-pyrazol-3-yl-κN (2))pyridine-κN]manganese(II)
title_short Bis(acetato-κ(2) O,O′)[2,6-bis­(1H-pyrazol-3-yl-κN (2))pyridine-κN]manganese(II)
title_sort bis(acetato-κ(2) o,o′)[2,6-bis­(1h-pyrazol-3-yl-κn (2))pyridine-κn]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099944/
https://www.ncbi.nlm.nih.gov/pubmed/21754009
http://dx.doi.org/10.1107/S1600536811010506
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