(Di-2-pyridyl­amine-κ(2) N,N′)[hydro­tris­(3,5-diphenyl­pyrazol-1-yl-κN (2))borato]nickel(II) bromide dichloro­methane monosolvate

In the title compound, [Ni(C(45)H(34)BN(6))(C(10)H(9)N(3))]Br·CH(2)Cl(2), the Ni(II) atom is five-coordinated by the tridentate hydro­tris­(3,5-diphenyl­pyrazol­yl)borate ligand and a bidentate di-2-pyridyl­amine ligand in a distorted square-pyramidal geometry. In the crystal, inter­molecular N—H⋯Br...

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Detalles Bibliográficos
Autores principales: Harding, David J., Harding, Phimphaka, Adams, Harry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099946/
https://www.ncbi.nlm.nih.gov/pubmed/21753990
http://dx.doi.org/10.1107/S1600536811010233
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author Harding, David J.
Harding, Phimphaka
Adams, Harry
author_facet Harding, David J.
Harding, Phimphaka
Adams, Harry
author_sort Harding, David J.
collection PubMed
description In the title compound, [Ni(C(45)H(34)BN(6))(C(10)H(9)N(3))]Br·CH(2)Cl(2), the Ni(II) atom is five-coordinated by the tridentate hydro­tris­(3,5-diphenyl­pyrazol­yl)borate ligand and a bidentate di-2-pyridyl­amine ligand in a distorted square-pyramidal geometry. In the crystal, inter­molecular N—H⋯Br and C—H⋯Br hydrogen bonds link the Ni complex cations and the Br(−) ions, forming a chain along the c axis.
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spelling pubmed-30999462011-07-13 (Di-2-pyridyl­amine-κ(2) N,N′)[hydro­tris­(3,5-diphenyl­pyrazol-1-yl-κN (2))borato]nickel(II) bromide dichloro­methane monosolvate Harding, David J. Harding, Phimphaka Adams, Harry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(45)H(34)BN(6))(C(10)H(9)N(3))]Br·CH(2)Cl(2), the Ni(II) atom is five-coordinated by the tridentate hydro­tris­(3,5-diphenyl­pyrazol­yl)borate ligand and a bidentate di-2-pyridyl­amine ligand in a distorted square-pyramidal geometry. In the crystal, inter­molecular N—H⋯Br and C—H⋯Br hydrogen bonds link the Ni complex cations and the Br(−) ions, forming a chain along the c axis. International Union of Crystallography 2011-03-23 /pmc/articles/PMC3099946/ /pubmed/21753990 http://dx.doi.org/10.1107/S1600536811010233 Text en © Harding et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Harding, David J.
Harding, Phimphaka
Adams, Harry
(Di-2-pyridyl­amine-κ(2) N,N′)[hydro­tris­(3,5-diphenyl­pyrazol-1-yl-κN (2))borato]nickel(II) bromide dichloro­methane monosolvate
title (Di-2-pyridyl­amine-κ(2) N,N′)[hydro­tris­(3,5-diphenyl­pyrazol-1-yl-κN (2))borato]nickel(II) bromide dichloro­methane monosolvate
title_full (Di-2-pyridyl­amine-κ(2) N,N′)[hydro­tris­(3,5-diphenyl­pyrazol-1-yl-κN (2))borato]nickel(II) bromide dichloro­methane monosolvate
title_fullStr (Di-2-pyridyl­amine-κ(2) N,N′)[hydro­tris­(3,5-diphenyl­pyrazol-1-yl-κN (2))borato]nickel(II) bromide dichloro­methane monosolvate
title_full_unstemmed (Di-2-pyridyl­amine-κ(2) N,N′)[hydro­tris­(3,5-diphenyl­pyrazol-1-yl-κN (2))borato]nickel(II) bromide dichloro­methane monosolvate
title_short (Di-2-pyridyl­amine-κ(2) N,N′)[hydro­tris­(3,5-diphenyl­pyrazol-1-yl-κN (2))borato]nickel(II) bromide dichloro­methane monosolvate
title_sort (di-2-pyridyl­amine-κ(2) n,n′)[hydro­tris­(3,5-diphenyl­pyrazol-1-yl-κn (2))borato]nickel(ii) bromide dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099946/
https://www.ncbi.nlm.nih.gov/pubmed/21753990
http://dx.doi.org/10.1107/S1600536811010233
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AT hardingphimphaka di2pyridylaminek2nnhydrotris35diphenylpyrazol1ylkn2boratonickeliibromidedichloromethanemonosolvate
AT adamsharry di2pyridylaminek2nnhydrotris35diphenylpyrazol1ylkn2boratonickeliibromidedichloromethanemonosolvate

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