catena-Poly[[bis­(pyridine-κN)cadmium]-di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N]

The asymmetric unit of the title compound, [Cd(NCS)(2)(C(5)H(5)N)(2)](n), consists of two crystallographically independent Cd(II) cations, four thio­cyanato anions and four pyridine ligands. The Cd(II) atoms are each coordinated by four N atoms from two pyridine ligands and two thio­cyanato anions,...

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Detalles Bibliográficos
Autores principales: Boeckmann, Jan, Jess, Inke, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099960/
https://www.ncbi.nlm.nih.gov/pubmed/21753993
http://dx.doi.org/10.1107/S1600536811009871
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author Boeckmann, Jan
Jess, Inke
Näther, Christian
author_facet Boeckmann, Jan
Jess, Inke
Näther, Christian
author_sort Boeckmann, Jan
collection PubMed
description The asymmetric unit of the title compound, [Cd(NCS)(2)(C(5)H(5)N)(2)](n), consists of two crystallographically independent Cd(II) cations, four thio­cyanato anions and four pyridine ligands. The Cd(II) atoms are each coordinated by four N atoms from two pyridine ligands and two thio­cyanato anions, each in a mutually cis orientation, and by two S atoms from two adjacent thio­cyanato anions within a slightly distorted octa­hedral coordination environment. The Cd(II) atoms are μ-1,3-bridged via the thio­cyanato anions into polymeric chains parallel to [001]. The Cd(II)⋯Cd(II) intra­chain separations range between 5.9688 (6) and 6.0195 (6) Å, whereas the shortest Cd(II)⋯Cd(II) inter­chain separations are 7.8272 (7) and 8.6312 (6) Å.
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spelling pubmed-30999602011-07-13 catena-Poly[[bis­(pyridine-κN)cadmium]-di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N] Boeckmann, Jan Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cd(NCS)(2)(C(5)H(5)N)(2)](n), consists of two crystallographically independent Cd(II) cations, four thio­cyanato anions and four pyridine ligands. The Cd(II) atoms are each coordinated by four N atoms from two pyridine ligands and two thio­cyanato anions, each in a mutually cis orientation, and by two S atoms from two adjacent thio­cyanato anions within a slightly distorted octa­hedral coordination environment. The Cd(II) atoms are μ-1,3-bridged via the thio­cyanato anions into polymeric chains parallel to [001]. The Cd(II)⋯Cd(II) intra­chain separations range between 5.9688 (6) and 6.0195 (6) Å, whereas the shortest Cd(II)⋯Cd(II) inter­chain separations are 7.8272 (7) and 8.6312 (6) Å. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3099960/ /pubmed/21753993 http://dx.doi.org/10.1107/S1600536811009871 Text en © Boeckmann et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boeckmann, Jan
Jess, Inke
Näther, Christian
catena-Poly[[bis­(pyridine-κN)cadmium]-di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N]
title catena-Poly[[bis­(pyridine-κN)cadmium]-di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_full catena-Poly[[bis­(pyridine-κN)cadmium]-di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_fullStr catena-Poly[[bis­(pyridine-κN)cadmium]-di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_full_unstemmed catena-Poly[[bis­(pyridine-κN)cadmium]-di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_short catena-Poly[[bis­(pyridine-κN)cadmium]-di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_sort catena-poly[[bis­(pyridine-κn)cadmium]-di-μ(2)-thio­cyanato-κ(2) n:s;κ(2) s:n]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099960/
https://www.ncbi.nlm.nih.gov/pubmed/21753993
http://dx.doi.org/10.1107/S1600536811009871
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AT jessinke catenapolybispyridinekncadmiumdim2thiocyanatok2nsk2sn
AT natherchristian catenapolybispyridinekncadmiumdim2thiocyanatok2nsk2sn

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