Cyanidotetra­kis­(trimethyl­phosphine)cobalt(I)

The title compound, [Co(CN)(C(3)H(9)P)(4)], was obtained as a product of the reaction of [Co(PMe(3))(4)] with a molar equivalent of 2,6-difluoro­benzonitrile in diethyl ether. This compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The cobalt(I)...

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Detalles Bibliográficos
Autores principales: Xu, Xiaofeng, Feng, Lei, Li, Xiaoyan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099961/
https://www.ncbi.nlm.nih.gov/pubmed/21754010
http://dx.doi.org/10.1107/S160053681101083X
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author Xu, Xiaofeng
Feng, Lei
Li, Xiaoyan
author_facet Xu, Xiaofeng
Feng, Lei
Li, Xiaoyan
author_sort Xu, Xiaofeng
collection PubMed
description The title compound, [Co(CN)(C(3)H(9)P)(4)], was obtained as a product of the reaction of [Co(PMe(3))(4)] with a molar equivalent of 2,6-difluoro­benzonitrile in diethyl ether. This compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The cobalt(I) atom has s trigonal–bipyramidal coordination enviroment in which the cyano group and one of the PMe(3) groups are in the axial positions.
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spelling pubmed-30999612011-07-13 Cyanidotetra­kis­(trimethyl­phosphine)cobalt(I) Xu, Xiaofeng Feng, Lei Li, Xiaoyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(CN)(C(3)H(9)P)(4)], was obtained as a product of the reaction of [Co(PMe(3))(4)] with a molar equivalent of 2,6-difluoro­benzonitrile in diethyl ether. This compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The cobalt(I) atom has s trigonal–bipyramidal coordination enviroment in which the cyano group and one of the PMe(3) groups are in the axial positions. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3099961/ /pubmed/21754010 http://dx.doi.org/10.1107/S160053681101083X Text en © Xu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Xiaofeng
Feng, Lei
Li, Xiaoyan
Cyanidotetra­kis­(trimethyl­phosphine)cobalt(I)
title Cyanidotetra­kis­(trimethyl­phosphine)cobalt(I)
title_full Cyanidotetra­kis­(trimethyl­phosphine)cobalt(I)
title_fullStr Cyanidotetra­kis­(trimethyl­phosphine)cobalt(I)
title_full_unstemmed Cyanidotetra­kis­(trimethyl­phosphine)cobalt(I)
title_short Cyanidotetra­kis­(trimethyl­phosphine)cobalt(I)
title_sort cyanidotetra­kis­(trimethyl­phosphine)cobalt(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099961/
https://www.ncbi.nlm.nih.gov/pubmed/21754010
http://dx.doi.org/10.1107/S160053681101083X
work_keys_str_mv AT xuxiaofeng cyanidotetrakistrimethylphosphinecobalti
AT fenglei cyanidotetrakistrimethylphosphinecobalti
AT lixiaoyan cyanidotetrakistrimethylphosphinecobalti

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