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Phen­yl(1-phenyl­sulfonyl-1H-indol-2-yl)methanone

The asymmetric unit of the title compound, C(21)H(15)NO(3)S, contains two crystallographically independent mol­ecules. As a result of the electron-withdrawing character of the phenyl­sulfonyl groups, the N—Csp (2) bond lengths are slightly longer than the anti­cipated value of approximately 1.35 Å f...

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Autores principales: Ranjith, S., SubbiahPandi, A., Govindan, E., Dhayalan, V., MohanaKrishnan, A. K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099964/
https://www.ncbi.nlm.nih.gov/pubmed/21754126
http://dx.doi.org/10.1107/S1600536811008439
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author Ranjith, S.
SubbiahPandi, A.
Govindan, E.
Dhayalan, V.
MohanaKrishnan, A. K.
author_facet Ranjith, S.
SubbiahPandi, A.
Govindan, E.
Dhayalan, V.
MohanaKrishnan, A. K.
author_sort Ranjith, S.
collection PubMed
description The asymmetric unit of the title compound, C(21)H(15)NO(3)S, contains two crystallographically independent mol­ecules. As a result of the electron-withdrawing character of the phenyl­sulfonyl groups, the N—Csp (2) bond lengths are slightly longer than the anti­cipated value of approximately 1.35 Å for N atoms with planar configurations. Both unique S atoms have a distorted tetra­hedral configuration. In each mol­ecule, the indole ring system is essentially planar (r.m.s. deviations for all non-H atoms of 0.020 and 0.023 Å). In one mol­ecule, the indole ring system makes dihedral angles of 65.7 (8) and 73.4 (8)°, respectively, with the benzene and phenyl rings [62.2 (7) and 72.1 (7)°, respectively, in the other mol­ecule].
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spelling pubmed-30999642011-07-13 Phen­yl(1-phenyl­sulfonyl-1H-indol-2-yl)methanone Ranjith, S. SubbiahPandi, A. Govindan, E. Dhayalan, V. MohanaKrishnan, A. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(21)H(15)NO(3)S, contains two crystallographically independent mol­ecules. As a result of the electron-withdrawing character of the phenyl­sulfonyl groups, the N—Csp (2) bond lengths are slightly longer than the anti­cipated value of approximately 1.35 Å for N atoms with planar configurations. Both unique S atoms have a distorted tetra­hedral configuration. In each mol­ecule, the indole ring system is essentially planar (r.m.s. deviations for all non-H atoms of 0.020 and 0.023 Å). In one mol­ecule, the indole ring system makes dihedral angles of 65.7 (8) and 73.4 (8)°, respectively, with the benzene and phenyl rings [62.2 (7) and 72.1 (7)°, respectively, in the other mol­ecule]. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3099964/ /pubmed/21754126 http://dx.doi.org/10.1107/S1600536811008439 Text en © Ranjith et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ranjith, S.
SubbiahPandi, A.
Govindan, E.
Dhayalan, V.
MohanaKrishnan, A. K.
Phen­yl(1-phenyl­sulfonyl-1H-indol-2-yl)methanone
title Phen­yl(1-phenyl­sulfonyl-1H-indol-2-yl)methanone
title_full Phen­yl(1-phenyl­sulfonyl-1H-indol-2-yl)methanone
title_fullStr Phen­yl(1-phenyl­sulfonyl-1H-indol-2-yl)methanone
title_full_unstemmed Phen­yl(1-phenyl­sulfonyl-1H-indol-2-yl)methanone
title_short Phen­yl(1-phenyl­sulfonyl-1H-indol-2-yl)methanone
title_sort phen­yl(1-phenyl­sulfonyl-1h-indol-2-yl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099964/
https://www.ncbi.nlm.nih.gov/pubmed/21754126
http://dx.doi.org/10.1107/S1600536811008439
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AT dhayalanv phenyl1phenylsulfonyl1hindol2ylmethanone
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