(E)-1-(4-Meth­oxy­anthracen-1-yl)-2-phenyl­diazene

The title compound, C(21)H(16)N(2)O, has an E-conformation about the diazene N=N bond. It is reasonably planar with the phenyl ring being inclined to the mean plane of the anthracene moiety [planar to within 0.077 (3) Å] by 6.43 (10)°. The crystal structure is stabilized by C—H⋯π and weak π–π inter­...

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Detalles Bibliográficos
Autores principales: Crochet, Aurelien, Fromm, Katharina M., Kurteva, Vanya, Antonov, Liudmil
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099966/
https://www.ncbi.nlm.nih.gov/pubmed/21754250
http://dx.doi.org/10.1107/S1600536811010932
Descripción
Sumario:The title compound, C(21)H(16)N(2)O, has an E-conformation about the diazene N=N bond. It is reasonably planar with the phenyl ring being inclined to the mean plane of the anthracene moiety [planar to within 0.077 (3) Å] by 6.43 (10)°. The crystal structure is stabilized by C—H⋯π and weak π–π inter­actions [centroid–centroid distances of 3.7192 (16) and 3.8382 (15) Å], leading to the formation of two-dimensional networks stacking along [001] and lying parallel to (110).

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