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Bis[dicyclohexyl(phenyl)phosphane-κP]silver(I) perchlorate dichloromethane monosolvate
In the title compound, [Ag{P(C(6)H(11))(2)(C(6)H(5))}(2)]ClO(4)·CH(2)Cl(2), the Ag(I) atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag—P = 2.3993 (4) and 2.4011 (4) Å; P—Ag—P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099967/ https://www.ncbi.nlm.nih.gov/pubmed/21753995 http://dx.doi.org/10.1107/S1600536811009822 |
Sumario: | In the title compound, [Ag{P(C(6)H(11))(2)(C(6)H(5))}(2)]ClO(4)·CH(2)Cl(2), the Ag(I) atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag—P = 2.3993 (4) and 2.4011 (4) Å; P—Ag—P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag⋯O(perchlorate) interaction of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the Ag(I) atom. Weak intermolecular C—H⋯O hydrogen-bonding interactions involving phenyl, cyclohexyl and dichloromethane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure. |
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