Cargando…

Bis[dicyclo­hexyl­(phenyl)­phosphane-κP]silver(I) perchlorate dichloro­methane monosolvate

In the title compound, [Ag{P(C(6)H(11))(2)(C(6)H(5))}(2)]ClO(4)·CH(2)Cl(2), the Ag(I) atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag—P = 2.3993 (4) and 2.4011 (4) Å; P—Ag—P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There...

Descripción completa

Detalles Bibliográficos
Autores principales: Munyaneza, Apollinaire, Meijboom, Reinout, Omondi, Bernard
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099967/
https://www.ncbi.nlm.nih.gov/pubmed/21753995
http://dx.doi.org/10.1107/S1600536811009822
Descripción
Sumario:In the title compound, [Ag{P(C(6)H(11))(2)(C(6)H(5))}(2)]ClO(4)·CH(2)Cl(2), the Ag(I) atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag—P = 2.3993 (4) and 2.4011 (4) Å; P—Ag—P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag⋯O(perchlorate) inter­action of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the Ag(I) atom. Weak inter­molecular C—H⋯O hydrogen-bonding inter­actions involving phenyl, cyclo­hexyl and dichloro­methane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure.