Bis[dicyclo­hexyl­(phenyl)­phosphane-κP]silver(I) perchlorate dichloro­methane monosolvate

In the title compound, [Ag{P(C(6)H(11))(2)(C(6)H(5))}(2)]ClO(4)·CH(2)Cl(2), the Ag(I) atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag—P = 2.3993 (4) and 2.4011 (4) Å; P—Ag—P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There...

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Detalles Bibliográficos
Autores principales: Munyaneza, Apollinaire, Meijboom, Reinout, Omondi, Bernard
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099967/
https://www.ncbi.nlm.nih.gov/pubmed/21753995
http://dx.doi.org/10.1107/S1600536811009822
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author Munyaneza, Apollinaire
Meijboom, Reinout
Omondi, Bernard
author_facet Munyaneza, Apollinaire
Meijboom, Reinout
Omondi, Bernard
author_sort Munyaneza, Apollinaire
collection PubMed
description In the title compound, [Ag{P(C(6)H(11))(2)(C(6)H(5))}(2)]ClO(4)·CH(2)Cl(2), the Ag(I) atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag—P = 2.3993 (4) and 2.4011 (4) Å; P—Ag—P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag⋯O(perchlorate) inter­action of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the Ag(I) atom. Weak inter­molecular C—H⋯O hydrogen-bonding inter­actions involving phenyl, cyclo­hexyl and dichloro­methane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure.
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spelling pubmed-30999672011-07-13 Bis[dicyclo­hexyl­(phenyl)­phosphane-κP]silver(I) perchlorate dichloro­methane monosolvate Munyaneza, Apollinaire Meijboom, Reinout Omondi, Bernard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag{P(C(6)H(11))(2)(C(6)H(5))}(2)]ClO(4)·CH(2)Cl(2), the Ag(I) atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag—P = 2.3993 (4) and 2.4011 (4) Å; P—Ag—P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag⋯O(perchlorate) inter­action of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the Ag(I) atom. Weak inter­molecular C—H⋯O hydrogen-bonding inter­actions involving phenyl, cyclo­hexyl and dichloro­methane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3099967/ /pubmed/21753995 http://dx.doi.org/10.1107/S1600536811009822 Text en © Munyaneza et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Munyaneza, Apollinaire
Meijboom, Reinout
Omondi, Bernard
Bis[dicyclo­hexyl­(phenyl)­phosphane-κP]silver(I) perchlorate dichloro­methane monosolvate
title Bis[dicyclo­hexyl­(phenyl)­phosphane-κP]silver(I) perchlorate dichloro­methane monosolvate
title_full Bis[dicyclo­hexyl­(phenyl)­phosphane-κP]silver(I) perchlorate dichloro­methane monosolvate
title_fullStr Bis[dicyclo­hexyl­(phenyl)­phosphane-κP]silver(I) perchlorate dichloro­methane monosolvate
title_full_unstemmed Bis[dicyclo­hexyl­(phenyl)­phosphane-κP]silver(I) perchlorate dichloro­methane monosolvate
title_short Bis[dicyclo­hexyl­(phenyl)­phosphane-κP]silver(I) perchlorate dichloro­methane monosolvate
title_sort bis[dicyclo­hexyl­(phenyl)­phosphane-κp]silver(i) perchlorate dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099967/
https://www.ncbi.nlm.nih.gov/pubmed/21753995
http://dx.doi.org/10.1107/S1600536811009822
work_keys_str_mv AT munyanezaapollinaire bisdicyclohexylphenylphosphanekpsilveriperchloratedichloromethanemonosolvate
AT meijboomreinout bisdicyclohexylphenylphosphanekpsilveriperchloratedichloromethanemonosolvate
AT omondibernard bisdicyclohexylphenylphosphanekpsilveriperchloratedichloromethanemonosolvate

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