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(η(3)-Allyl)bromido(1-phenyl-1H-imidazole-κN (3))palladium(II)
The title compound, [PdBr(C(3)H(5))(C(9)H(8)N(2))], was synthesized by the reaction of the allylpalladium(II) bromide dimer and 1-phenyl-1H-imidazole. The Pd atom is coordinated by one allyl group [in η(3) mode, the central CH group of the allyl group is disordered over two sets of sites in a 0.668...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099968/ https://www.ncbi.nlm.nih.gov/pubmed/21753975 http://dx.doi.org/10.1107/S1600536811008798 |
Sumario: | The title compound, [PdBr(C(3)H(5))(C(9)H(8)N(2))], was synthesized by the reaction of the allylpalladium(II) bromide dimer and 1-phenyl-1H-imidazole. The Pd atom is coordinated by one allyl group [in η(3) mode, the central CH group of the allyl group is disordered over two sets of sites in a 0.668 (5):0.332 (5) ratio], one bromide anion and a 1-phenyl-1H-imidazole ligand. Intramolecular face-to-face π–π stacking interactions occur between adjacent phenyl or imidazole groups, with centroid–centroid distances in the range 3.877 (1)–3.6596 (6) Å, forming a supramolecular chain along [100]. |
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