(η(3)-All­yl)bromido(1-phenyl-1H-imidazole-κN (3))palladium(II)

The title compound, [PdBr(C(3)H(5))(C(9)H(8)N(2))], was synthesized by the reaction of the allyl­palladium(II) bromide dimer and 1-phenyl-1H-imidazole. The Pd atom is coordinated by one allyl group [in η(3) mode, the central CH group of the allyl group is disordered over two sets of sites in a 0.668...

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Detalles Bibliográficos
Autores principales: Huang, Jiangying, Zhang, Xiao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099968/
https://www.ncbi.nlm.nih.gov/pubmed/21753975
http://dx.doi.org/10.1107/S1600536811008798
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author Huang, Jiangying
Zhang, Xiao
author_facet Huang, Jiangying
Zhang, Xiao
author_sort Huang, Jiangying
collection PubMed
description The title compound, [PdBr(C(3)H(5))(C(9)H(8)N(2))], was synthesized by the reaction of the allyl­palladium(II) bromide dimer and 1-phenyl-1H-imidazole. The Pd atom is coordinated by one allyl group [in η(3) mode, the central CH group of the allyl group is disordered over two sets of sites in a 0.668 (5):0.332 (5) ratio], one bromide anion and a 1-phenyl-1H-imidazole ligand. Intra­molecular face-to-face π–π stacking inter­actions occur between adjacent phenyl or imidazole groups, with centroid–centroid distances in the range 3.877 (1)–3.6596 (6) Å, forming a supra­molecular chain along [100].
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spelling pubmed-30999682011-07-13 (η(3)-All­yl)bromido(1-phenyl-1H-imidazole-κN (3))palladium(II) Huang, Jiangying Zhang, Xiao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PdBr(C(3)H(5))(C(9)H(8)N(2))], was synthesized by the reaction of the allyl­palladium(II) bromide dimer and 1-phenyl-1H-imidazole. The Pd atom is coordinated by one allyl group [in η(3) mode, the central CH group of the allyl group is disordered over two sets of sites in a 0.668 (5):0.332 (5) ratio], one bromide anion and a 1-phenyl-1H-imidazole ligand. Intra­molecular face-to-face π–π stacking inter­actions occur between adjacent phenyl or imidazole groups, with centroid–centroid distances in the range 3.877 (1)–3.6596 (6) Å, forming a supra­molecular chain along [100]. International Union of Crystallography 2011-03-15 /pmc/articles/PMC3099968/ /pubmed/21753975 http://dx.doi.org/10.1107/S1600536811008798 Text en © Huang and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Jiangying
Zhang, Xiao
(η(3)-All­yl)bromido(1-phenyl-1H-imidazole-κN (3))palladium(II)
title (η(3)-All­yl)bromido(1-phenyl-1H-imidazole-κN (3))palladium(II)
title_full (η(3)-All­yl)bromido(1-phenyl-1H-imidazole-κN (3))palladium(II)
title_fullStr (η(3)-All­yl)bromido(1-phenyl-1H-imidazole-κN (3))palladium(II)
title_full_unstemmed (η(3)-All­yl)bromido(1-phenyl-1H-imidazole-κN (3))palladium(II)
title_short (η(3)-All­yl)bromido(1-phenyl-1H-imidazole-κN (3))palladium(II)
title_sort (η(3)-all­yl)bromido(1-phenyl-1h-imidazole-κn (3))palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099968/
https://www.ncbi.nlm.nih.gov/pubmed/21753975
http://dx.doi.org/10.1107/S1600536811008798
work_keys_str_mv AT huangjiangying ē3allylbromido1phenyl1himidazolekn3palladiumii
AT zhangxiao ē3allylbromido1phenyl1himidazolekn3palladiumii

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