Ethyl 4-acetyl-5-oxo-3-phenyl­hexa­noate

The reaction of ethyl 3-bromo-3-phenyl­propano­ate with pentane-2,4-dione, in the presence of palladium(II) acetate and triphenyl­phosphine, in dimethyl­formamide, unexpectedly gave the title product, C(16)H(20)O(4). The mol­ecule contains one chiral C atom but the crystal is racemic. In the crystal...

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Detalles Bibliográficos
Autores principales: Wang, Hongwei, Hu, Yimin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099969/
https://www.ncbi.nlm.nih.gov/pubmed/21754190
http://dx.doi.org/10.1107/S160053681100955X
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author Wang, Hongwei
Hu, Yimin
author_facet Wang, Hongwei
Hu, Yimin
author_sort Wang, Hongwei
collection PubMed
description The reaction of ethyl 3-bromo-3-phenyl­propano­ate with pentane-2,4-dione, in the presence of palladium(II) acetate and triphenyl­phosphine, in dimethyl­formamide, unexpectedly gave the title product, C(16)H(20)O(4). The mol­ecule contains one chiral C atom but the crystal is racemic. In the crystal, neighboring mol­ecules form a chain along [100] through three weak C—H⋯O inter­actions. Furthermore, a double-stranded structure is formed through weak C—H⋯O inter­actions between two parallel chains.
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spelling pubmed-30999692011-07-13 Ethyl 4-acetyl-5-oxo-3-phenyl­hexa­noate Wang, Hongwei Hu, Yimin Acta Crystallogr Sect E Struct Rep Online Organic Papers The reaction of ethyl 3-bromo-3-phenyl­propano­ate with pentane-2,4-dione, in the presence of palladium(II) acetate and triphenyl­phosphine, in dimethyl­formamide, unexpectedly gave the title product, C(16)H(20)O(4). The mol­ecule contains one chiral C atom but the crystal is racemic. In the crystal, neighboring mol­ecules form a chain along [100] through three weak C—H⋯O inter­actions. Furthermore, a double-stranded structure is formed through weak C—H⋯O inter­actions between two parallel chains. International Union of Crystallography 2011-03-19 /pmc/articles/PMC3099969/ /pubmed/21754190 http://dx.doi.org/10.1107/S160053681100955X Text en © Wang and Hu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Hongwei
Hu, Yimin
Ethyl 4-acetyl-5-oxo-3-phenyl­hexa­noate
title Ethyl 4-acetyl-5-oxo-3-phenyl­hexa­noate
title_full Ethyl 4-acetyl-5-oxo-3-phenyl­hexa­noate
title_fullStr Ethyl 4-acetyl-5-oxo-3-phenyl­hexa­noate
title_full_unstemmed Ethyl 4-acetyl-5-oxo-3-phenyl­hexa­noate
title_short Ethyl 4-acetyl-5-oxo-3-phenyl­hexa­noate
title_sort ethyl 4-acetyl-5-oxo-3-phenyl­hexa­noate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099969/
https://www.ncbi.nlm.nih.gov/pubmed/21754190
http://dx.doi.org/10.1107/S160053681100955X
work_keys_str_mv AT wanghongwei ethyl4acetyl5oxo3phenylhexanoate
AT huyimin ethyl4acetyl5oxo3phenylhexanoate

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