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Poly[aqua(μ(3)-pyridazine-4-carboxylato-κ(2) O:O:O′)lithium]
The structure of the title compound, [Li(C(5)H(3)N(2)O(2))(H(2)O)](n), is composed of centrosymmetric dimers in which two Li(I) ions are bridged by a carboxylate O atom, each donated by a ligand, acting in a bidentate mode. The second carboxylato O atoms bridge the dimers to Li(I) ions in adjacent...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099971/ https://www.ncbi.nlm.nih.gov/pubmed/21753953 http://dx.doi.org/10.1107/S1600536811008634 |
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author | Starosta, Wojciech Leciejewicz, Janusz |
author_facet | Starosta, Wojciech Leciejewicz, Janusz |
author_sort | Starosta, Wojciech |
collection | PubMed |
description | The structure of the title compound, [Li(C(5)H(3)N(2)O(2))(H(2)O)](n), is composed of centrosymmetric dimers in which two Li(I) ions are bridged by a carboxylate O atom, each donated by a ligand, acting in a bidentate mode. The second carboxylato O atoms bridge the dimers to Li(I) ions in adjacent dimers, forming molecular layers parallel to (001). Each Li(I) ion is coordinated by two bridging carboxylate O atoms, a bridging carboxylate O atom donated by the adjacent dimer and an aqua O atom, resulting in a distorted tetrahedral coordination geometry. The layers are held together by O—H⋯N hydrogen bonds in which coordinated water O atoms act as donors and ligand hetero-ring N atoms as acceptors. |
format | Text |
id | pubmed-3099971 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30999712011-07-13 Poly[aqua(μ(3)-pyridazine-4-carboxylato-κ(2) O:O:O′)lithium] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Li(C(5)H(3)N(2)O(2))(H(2)O)](n), is composed of centrosymmetric dimers in which two Li(I) ions are bridged by a carboxylate O atom, each donated by a ligand, acting in a bidentate mode. The second carboxylato O atoms bridge the dimers to Li(I) ions in adjacent dimers, forming molecular layers parallel to (001). Each Li(I) ion is coordinated by two bridging carboxylate O atoms, a bridging carboxylate O atom donated by the adjacent dimer and an aqua O atom, resulting in a distorted tetrahedral coordination geometry. The layers are held together by O—H⋯N hydrogen bonds in which coordinated water O atoms act as donors and ligand hetero-ring N atoms as acceptors. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3099971/ /pubmed/21753953 http://dx.doi.org/10.1107/S1600536811008634 Text en © Starosta and Leciejewicz 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Starosta, Wojciech Leciejewicz, Janusz Poly[aqua(μ(3)-pyridazine-4-carboxylato-κ(2) O:O:O′)lithium] |
title | Poly[aqua(μ(3)-pyridazine-4-carboxylato-κ(2)
O:O:O′)lithium] |
title_full | Poly[aqua(μ(3)-pyridazine-4-carboxylato-κ(2)
O:O:O′)lithium] |
title_fullStr | Poly[aqua(μ(3)-pyridazine-4-carboxylato-κ(2)
O:O:O′)lithium] |
title_full_unstemmed | Poly[aqua(μ(3)-pyridazine-4-carboxylato-κ(2)
O:O:O′)lithium] |
title_short | Poly[aqua(μ(3)-pyridazine-4-carboxylato-κ(2)
O:O:O′)lithium] |
title_sort | poly[aqua(μ(3)-pyridazine-4-carboxylato-κ(2)
o:o:o′)lithium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099971/ https://www.ncbi.nlm.nih.gov/pubmed/21753953 http://dx.doi.org/10.1107/S1600536811008634 |
work_keys_str_mv | AT starostawojciech polyaquam3pyridazine4carboxylatok2ooolithium AT leciejewiczjanusz polyaquam3pyridazine4carboxylatok2ooolithium |