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Poly[aqua­(μ(3)-pyridazine-4-carboxyl­ato-κ(2) O:O:O′)lithium]

The structure of the title compound, [Li(C(5)H(3)N(2)O(2))(H(2)O)](n), is composed of centrosymmetric dimers in which two Li(I) ions are bridged by a carboxyl­ate O atom, each donated by a ligand, acting in a bidentate mode. The second carboxyl­ato O atoms bridge the dimers to Li(I) ions in adjacent...

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Detalles Bibliográficos
Autores principales: Starosta, Wojciech, Leciejewicz, Janusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099971/
https://www.ncbi.nlm.nih.gov/pubmed/21753953
http://dx.doi.org/10.1107/S1600536811008634
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author Starosta, Wojciech
Leciejewicz, Janusz
author_facet Starosta, Wojciech
Leciejewicz, Janusz
author_sort Starosta, Wojciech
collection PubMed
description The structure of the title compound, [Li(C(5)H(3)N(2)O(2))(H(2)O)](n), is composed of centrosymmetric dimers in which two Li(I) ions are bridged by a carboxyl­ate O atom, each donated by a ligand, acting in a bidentate mode. The second carboxyl­ato O atoms bridge the dimers to Li(I) ions in adjacent dimers, forming mol­ecular layers parallel to (001). Each Li(I) ion is coordinated by two bridging carboxyl­ate O atoms, a bridging carboxyl­ate O atom donated by the adjacent dimer and an aqua O atom, resulting in a distorted tetra­hedral coordination geometry. The layers are held together by O—H⋯N hydrogen bonds in which coordinated water O atoms act as donors and ligand hetero-ring N atoms as acceptors.
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spelling pubmed-30999712011-07-13 Poly[aqua­(μ(3)-pyridazine-4-carboxyl­ato-κ(2) O:O:O′)lithium] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Li(C(5)H(3)N(2)O(2))(H(2)O)](n), is composed of centrosymmetric dimers in which two Li(I) ions are bridged by a carboxyl­ate O atom, each donated by a ligand, acting in a bidentate mode. The second carboxyl­ato O atoms bridge the dimers to Li(I) ions in adjacent dimers, forming mol­ecular layers parallel to (001). Each Li(I) ion is coordinated by two bridging carboxyl­ate O atoms, a bridging carboxyl­ate O atom donated by the adjacent dimer and an aqua O atom, resulting in a distorted tetra­hedral coordination geometry. The layers are held together by O—H⋯N hydrogen bonds in which coordinated water O atoms act as donors and ligand hetero-ring N atoms as acceptors. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3099971/ /pubmed/21753953 http://dx.doi.org/10.1107/S1600536811008634 Text en © Starosta and Leciejewicz 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Starosta, Wojciech
Leciejewicz, Janusz
Poly[aqua­(μ(3)-pyridazine-4-carboxyl­ato-κ(2) O:O:O′)lithium]
title Poly[aqua­(μ(3)-pyridazine-4-carboxyl­ato-κ(2) O:O:O′)lithium]
title_full Poly[aqua­(μ(3)-pyridazine-4-carboxyl­ato-κ(2) O:O:O′)lithium]
title_fullStr Poly[aqua­(μ(3)-pyridazine-4-carboxyl­ato-κ(2) O:O:O′)lithium]
title_full_unstemmed Poly[aqua­(μ(3)-pyridazine-4-carboxyl­ato-κ(2) O:O:O′)lithium]
title_short Poly[aqua­(μ(3)-pyridazine-4-carboxyl­ato-κ(2) O:O:O′)lithium]
title_sort poly[aqua­(μ(3)-pyridazine-4-carboxyl­ato-κ(2) o:o:o′)lithium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099971/
https://www.ncbi.nlm.nih.gov/pubmed/21753953
http://dx.doi.org/10.1107/S1600536811008634
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