Cargando…
Poly[μ-(5,5′-diazenediylditetrazolido)-dicaesium]
The asymmetric unit of the title compound, [Cs(2)(C(2)N(10))](n), comprises a Cs(+) cation, and one-half of a 5,5′-diazenediylditetrazolide anion. The Cs(+) cation is six-coordinated by N atoms from six 5,5′-diazenediylditetrazolide ligands. Each 5,5′-diazenediylditetrazolide ligand is surrounded...
| Autor principal: | |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099978/ https://www.ncbi.nlm.nih.gov/pubmed/21753972 http://dx.doi.org/10.1107/S1600536811008312 |
| Sumario: | The asymmetric unit of the title compound, [Cs(2)(C(2)N(10))](n), comprises a Cs(+) cation, and one-half of a 5,5′-diazenediylditetrazolide anion. The Cs(+) cation is six-coordinated by N atoms from six 5,5′-diazenediylditetrazolide ligands. Each 5,5′-diazenediylditetrazolide ligand is surrounded by 12 Cs(+) cations, coordinating through ten N atoms. The Cs(+) cations are arranged in a chain along the a-axis direction with a Cs⋯Cs separation of 4.4393 (10) Å. Such coordination leads to the formation of the three-dimensional framework. |
|---|