1,2-Dihydro-9H-carbazole-4(3H)-thione

The crystal structure of the title compound, C(12)H(11)NS, features parallel chains of alternating N—H⋯S hydrogen-bonded mirror-image conformers along [10[Image: see text]]. The mol­ecular conformation is that of an envelope, with all of the framework atoms except one close to a mean plane (rms devi...

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Detalles Bibliográficos
Autores principales: Phelan, W. Adam, Ngu-Schwemlein, Maria, Fronczek, Frank R., McLaughlin, Mark L., Watkins, Steven F.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099987/
https://www.ncbi.nlm.nih.gov/pubmed/21754054
http://dx.doi.org/10.1107/S1600536811006623
Descripción
Sumario:The crystal structure of the title compound, C(12)H(11)NS, features parallel chains of alternating N—H⋯S hydrogen-bonded mirror-image conformers along [10[Image: see text]]. The mol­ecular conformation is that of an envelope, with all of the framework atoms except one close to a mean plane (rms deviation 0.054 Å); one C atom of the cyclo­hexene­thione ring forms the envelope flap, which makes a dihedral angle of 48.6 (1)° with the rest of the mol­ecule. There is a π–π* inter­action between pairs of enanti­omers in adjacent chains; the distance between parallel planes is 3.466 (1) Å.

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