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tert-Butyl 3-benzyl-3-[(E)-2-benzylidene-3-oxocyclopentyl]-2-oxoindoline-1-carboxylate
In the title compound, C(32)H(31)NO(4), the dihedral angles between the indoline ring and the two phenyl rings are 48.11 (9) and 66.55 (9)°. The molecular conformation is stabilized by a weak intramolecular π–π stacking interaction [centroid–centroid distance = 3.6377 (7) Å]. The crystal structure...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099990/ https://www.ncbi.nlm.nih.gov/pubmed/21754139 http://dx.doi.org/10.1107/S160053681100691X |
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author | Qiao, Zhen Liu, Li Wang, Dong |
author_facet | Qiao, Zhen Liu, Li Wang, Dong |
author_sort | Qiao, Zhen |
collection | PubMed |
description | In the title compound, C(32)H(31)NO(4), the dihedral angles between the indoline ring and the two phenyl rings are 48.11 (9) and 66.55 (9)°. The molecular conformation is stabilized by a weak intramolecular π–π stacking interaction [centroid–centroid distance = 3.6377 (7) Å]. The crystal structure is stabilized by intermolecular C—H⋯O hydrogen bonds, which form chains along the b axis. |
format | Text |
id | pubmed-3099990 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30999902011-07-13 tert-Butyl 3-benzyl-3-[(E)-2-benzylidene-3-oxocyclopentyl]-2-oxoindoline-1-carboxylate Qiao, Zhen Liu, Li Wang, Dong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(32)H(31)NO(4), the dihedral angles between the indoline ring and the two phenyl rings are 48.11 (9) and 66.55 (9)°. The molecular conformation is stabilized by a weak intramolecular π–π stacking interaction [centroid–centroid distance = 3.6377 (7) Å]. The crystal structure is stabilized by intermolecular C—H⋯O hydrogen bonds, which form chains along the b axis. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3099990/ /pubmed/21754139 http://dx.doi.org/10.1107/S160053681100691X Text en © Qiao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Qiao, Zhen Liu, Li Wang, Dong tert-Butyl 3-benzyl-3-[(E)-2-benzylidene-3-oxocyclopentyl]-2-oxoindoline-1-carboxylate |
title |
tert-Butyl 3-benzyl-3-[(E)-2-benzylidene-3-oxocyclopentyl]-2-oxoindoline-1-carboxylate |
title_full |
tert-Butyl 3-benzyl-3-[(E)-2-benzylidene-3-oxocyclopentyl]-2-oxoindoline-1-carboxylate |
title_fullStr |
tert-Butyl 3-benzyl-3-[(E)-2-benzylidene-3-oxocyclopentyl]-2-oxoindoline-1-carboxylate |
title_full_unstemmed |
tert-Butyl 3-benzyl-3-[(E)-2-benzylidene-3-oxocyclopentyl]-2-oxoindoline-1-carboxylate |
title_short |
tert-Butyl 3-benzyl-3-[(E)-2-benzylidene-3-oxocyclopentyl]-2-oxoindoline-1-carboxylate |
title_sort | tert-butyl 3-benzyl-3-[(e)-2-benzylidene-3-oxocyclopentyl]-2-oxoindoline-1-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099990/ https://www.ncbi.nlm.nih.gov/pubmed/21754139 http://dx.doi.org/10.1107/S160053681100691X |
work_keys_str_mv | AT qiaozhen tertbutyl3benzyl3e2benzylidene3oxocyclopentyl2oxoindoline1carboxylate AT liuli tertbutyl3benzyl3e2benzylidene3oxocyclopentyl2oxoindoline1carboxylate AT wangdong tertbutyl3benzyl3e2benzylidene3oxocyclopentyl2oxoindoline1carboxylate |