cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichloridocobalt(II) trihydrate

In the title complex, [CoCl(2)(C(10)H(8)N(2))(2)]·3H(2)O, the Co(II) ion is situated on a twofold rotation axis and exhibits a slightly distorted octa­hedral geometry and is chelated by four N atoms of the two bidentate 2,2′-bipyridine ligands and two Cl(−) ions. The crystal packing is stabilized by...

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Detalles Bibliográficos
Autores principales: Arun Kumar, K., Amuthaselvi, M., Dayalan, A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099996/
https://www.ncbi.nlm.nih.gov/pubmed/21753983
http://dx.doi.org/10.1107/S1600536811009251
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author Arun Kumar, K.
Amuthaselvi, M.
Dayalan, A.
author_facet Arun Kumar, K.
Amuthaselvi, M.
Dayalan, A.
author_sort Arun Kumar, K.
collection PubMed
description In the title complex, [CoCl(2)(C(10)H(8)N(2))(2)]·3H(2)O, the Co(II) ion is situated on a twofold rotation axis and exhibits a slightly distorted octa­hedral geometry and is chelated by four N atoms of the two bidentate 2,2′-bipyridine ligands and two Cl(−) ions. The crystal packing is stabilized by hydrogen bonding formed between chloride ions and adjacent water mol­ecules. One of the two independent water molecules in the asymmetric unit is disordered over two sets of sites, each on a twofold rotation axis, in a 0.734 (17):0.269 (17) ratio.
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spelling pubmed-30999962011-07-13 cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichloridocobalt(II) trihydrate Arun Kumar, K. Amuthaselvi, M. Dayalan, A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CoCl(2)(C(10)H(8)N(2))(2)]·3H(2)O, the Co(II) ion is situated on a twofold rotation axis and exhibits a slightly distorted octa­hedral geometry and is chelated by four N atoms of the two bidentate 2,2′-bipyridine ligands and two Cl(−) ions. The crystal packing is stabilized by hydrogen bonding formed between chloride ions and adjacent water mol­ecules. One of the two independent water molecules in the asymmetric unit is disordered over two sets of sites, each on a twofold rotation axis, in a 0.734 (17):0.269 (17) ratio. International Union of Crystallography 2011-03-19 /pmc/articles/PMC3099996/ /pubmed/21753983 http://dx.doi.org/10.1107/S1600536811009251 Text en © Arun Kumar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arun Kumar, K.
Amuthaselvi, M.
Dayalan, A.
cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichloridocobalt(II) trihydrate
title cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichloridocobalt(II) trihydrate
title_full cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichloridocobalt(II) trihydrate
title_fullStr cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichloridocobalt(II) trihydrate
title_full_unstemmed cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichloridocobalt(II) trihydrate
title_short cis-Bis(2,2′-bipyridine-κ(2) N,N′)dichloridocobalt(II) trihydrate
title_sort cis-bis(2,2′-bipyridine-κ(2) n,n′)dichloridocobalt(ii) trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099996/
https://www.ncbi.nlm.nih.gov/pubmed/21753983
http://dx.doi.org/10.1107/S1600536811009251
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AT amuthaselvim cisbis22bipyridinek2nndichloridocobaltiitrihydrate
AT dayalana cisbis22bipyridinek2nndichloridocobaltiitrihydrate

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