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3-[(1-Benzyl-1H-1,2,3-triazol-5-yl)meth­yl]-6-bromo-2-phenyl-3H-imidazo[4,5-b]pyridine

There are two crystallographically independent mol­ecules in the asymmetric unit of the title compound, C(22)H(17)BrN(6). The dihedral angles between the imidazo[4,5-b]pyridine mean plane and the phenyl rings are 20.4 (2) and 24.0 (2)° in the two mol­ecules. The orientation of triazoles compared to...

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Detalles Bibliográficos
Autores principales: Ouzidan, Younes, Kandri Rodi, Youssef, Fronczek, Frank R., Venkatraman, Ramaiyer, Essassi, El Mokhtar, El Ammari, Lahcen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099998/
https://www.ncbi.nlm.nih.gov/pubmed/21754166
http://dx.doi.org/10.1107/S1600536811009123
Descripción
Sumario:There are two crystallographically independent mol­ecules in the asymmetric unit of the title compound, C(22)H(17)BrN(6). The dihedral angles between the imidazo[4,5-b]pyridine mean plane and the phenyl rings are 20.4 (2) and 24.0 (2)° in the two mol­ecules. The orientation of triazoles compared to the imidazo[4,5-b]pyridine system is almost the same in both mol­ecules, with dihedral angles of 64.2 (2) and 65.1 (2)°. However, the main difference between the two mol­ecules lies in the arrangement of the phenyl groups compared to imidazo[4,5-b]pyridine in each mol­ecule. Indeed, in the first mol­ecule the dihedral angle between the plane of the phenyl ring and that of the imidazo[4,5-b]pyridine system is 67.7 (2)°, while in the second mol­ecule the plane of the phenyl ring is almost perpendicular to that of the imidazo[4,5-b]pyridine system with a dihedral angle of 86.0 (2)°.