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3-[(1-Benzyl-1H-1,2,3-triazol-5-yl)meth­yl]-6-bromo-2-phenyl-3H-imidazo[4,5-b]pyridine

There are two crystallographically independent mol­ecules in the asymmetric unit of the title compound, C(22)H(17)BrN(6). The dihedral angles between the imidazo[4,5-b]pyridine mean plane and the phenyl rings are 20.4 (2) and 24.0 (2)° in the two mol­ecules. The orientation of triazoles compared to...

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Autores principales: Ouzidan, Younes, Kandri Rodi, Youssef, Fronczek, Frank R., Venkatraman, Ramaiyer, Essassi, El Mokhtar, El Ammari, Lahcen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099998/
https://www.ncbi.nlm.nih.gov/pubmed/21754166
http://dx.doi.org/10.1107/S1600536811009123
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author Ouzidan, Younes
Kandri Rodi, Youssef
Fronczek, Frank R.
Venkatraman, Ramaiyer
Essassi, El Mokhtar
El Ammari, Lahcen
author_facet Ouzidan, Younes
Kandri Rodi, Youssef
Fronczek, Frank R.
Venkatraman, Ramaiyer
Essassi, El Mokhtar
El Ammari, Lahcen
author_sort Ouzidan, Younes
collection PubMed
description There are two crystallographically independent mol­ecules in the asymmetric unit of the title compound, C(22)H(17)BrN(6). The dihedral angles between the imidazo[4,5-b]pyridine mean plane and the phenyl rings are 20.4 (2) and 24.0 (2)° in the two mol­ecules. The orientation of triazoles compared to the imidazo[4,5-b]pyridine system is almost the same in both mol­ecules, with dihedral angles of 64.2 (2) and 65.1 (2)°. However, the main difference between the two mol­ecules lies in the arrangement of the phenyl groups compared to imidazo[4,5-b]pyridine in each mol­ecule. Indeed, in the first mol­ecule the dihedral angle between the plane of the phenyl ring and that of the imidazo[4,5-b]pyridine system is 67.7 (2)°, while in the second mol­ecule the plane of the phenyl ring is almost perpendicular to that of the imidazo[4,5-b]pyridine system with a dihedral angle of 86.0 (2)°.
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spelling pubmed-30999982011-07-13 3-[(1-Benzyl-1H-1,2,3-triazol-5-yl)meth­yl]-6-bromo-2-phenyl-3H-imidazo[4,5-b]pyridine Ouzidan, Younes Kandri Rodi, Youssef Fronczek, Frank R. Venkatraman, Ramaiyer Essassi, El Mokhtar El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two crystallographically independent mol­ecules in the asymmetric unit of the title compound, C(22)H(17)BrN(6). The dihedral angles between the imidazo[4,5-b]pyridine mean plane and the phenyl rings are 20.4 (2) and 24.0 (2)° in the two mol­ecules. The orientation of triazoles compared to the imidazo[4,5-b]pyridine system is almost the same in both mol­ecules, with dihedral angles of 64.2 (2) and 65.1 (2)°. However, the main difference between the two mol­ecules lies in the arrangement of the phenyl groups compared to imidazo[4,5-b]pyridine in each mol­ecule. Indeed, in the first mol­ecule the dihedral angle between the plane of the phenyl ring and that of the imidazo[4,5-b]pyridine system is 67.7 (2)°, while in the second mol­ecule the plane of the phenyl ring is almost perpendicular to that of the imidazo[4,5-b]pyridine system with a dihedral angle of 86.0 (2)°. International Union of Crystallography 2011-03-15 /pmc/articles/PMC3099998/ /pubmed/21754166 http://dx.doi.org/10.1107/S1600536811009123 Text en © Ouzidan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ouzidan, Younes
Kandri Rodi, Youssef
Fronczek, Frank R.
Venkatraman, Ramaiyer
Essassi, El Mokhtar
El Ammari, Lahcen
3-[(1-Benzyl-1H-1,2,3-triazol-5-yl)meth­yl]-6-bromo-2-phenyl-3H-imidazo[4,5-b]pyridine
title 3-[(1-Benzyl-1H-1,2,3-triazol-5-yl)meth­yl]-6-bromo-2-phenyl-3H-imidazo[4,5-b]pyridine
title_full 3-[(1-Benzyl-1H-1,2,3-triazol-5-yl)meth­yl]-6-bromo-2-phenyl-3H-imidazo[4,5-b]pyridine
title_fullStr 3-[(1-Benzyl-1H-1,2,3-triazol-5-yl)meth­yl]-6-bromo-2-phenyl-3H-imidazo[4,5-b]pyridine
title_full_unstemmed 3-[(1-Benzyl-1H-1,2,3-triazol-5-yl)meth­yl]-6-bromo-2-phenyl-3H-imidazo[4,5-b]pyridine
title_short 3-[(1-Benzyl-1H-1,2,3-triazol-5-yl)meth­yl]-6-bromo-2-phenyl-3H-imidazo[4,5-b]pyridine
title_sort 3-[(1-benzyl-1h-1,2,3-triazol-5-yl)meth­yl]-6-bromo-2-phenyl-3h-imidazo[4,5-b]pyridine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099998/
https://www.ncbi.nlm.nih.gov/pubmed/21754166
http://dx.doi.org/10.1107/S1600536811009123
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