2-Methyl­anilinium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate methanol monosolvate

In the anion of the title compound, C(7)H(10)N(+)·C(9)H(3)Br(4)O(4) (−)·CH(3)O, the dihedral angles formed by the benzene ring and the mean planes of the carboxyl­ate and meth­oxy­carbonyl groups are 74.8 (5) and 75.0 (5)°, respectively. In the crystal, inter­molecular N—H⋯O and O—H⋯O hydrogen bonds...

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Detalles Bibliográficos
Autor principal: Li, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099999/
https://www.ncbi.nlm.nih.gov/pubmed/21754174
http://dx.doi.org/10.1107/S1600536811008543
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author Li, Jian
author_facet Li, Jian
author_sort Li, Jian
collection PubMed
description In the anion of the title compound, C(7)H(10)N(+)·C(9)H(3)Br(4)O(4) (−)·CH(3)O, the dihedral angles formed by the benzene ring and the mean planes of the carboxyl­ate and meth­oxy­carbonyl groups are 74.8 (5) and 75.0 (5)°, respectively. In the crystal, inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the components into chains along [100]. Additional stabilization is provided by weak inter­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-30999992011-07-13 2-Methyl­anilinium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate methanol monosolvate Li, Jian Acta Crystallogr Sect E Struct Rep Online Organic Papers In the anion of the title compound, C(7)H(10)N(+)·C(9)H(3)Br(4)O(4) (−)·CH(3)O, the dihedral angles formed by the benzene ring and the mean planes of the carboxyl­ate and meth­oxy­carbonyl groups are 74.8 (5) and 75.0 (5)°, respectively. In the crystal, inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the components into chains along [100]. Additional stabilization is provided by weak inter­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2011-03-15 /pmc/articles/PMC3099999/ /pubmed/21754174 http://dx.doi.org/10.1107/S1600536811008543 Text en © Jian Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Jian
2-Methyl­anilinium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate methanol monosolvate
title 2-Methyl­anilinium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate methanol monosolvate
title_full 2-Methyl­anilinium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate methanol monosolvate
title_fullStr 2-Methyl­anilinium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate methanol monosolvate
title_full_unstemmed 2-Methyl­anilinium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate methanol monosolvate
title_short 2-Methyl­anilinium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate methanol monosolvate
title_sort 2-methyl­anilinium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099999/
https://www.ncbi.nlm.nih.gov/pubmed/21754174
http://dx.doi.org/10.1107/S1600536811008543
work_keys_str_mv AT lijian 2methylanilinium3456tetrabromo2methoxycarbonylbenzoatemethanolmonosolvate

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