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(Carbonato-κ(2) O,O′)bis­(di-2-pyridyl­amine-κ(2) N,N′)cobalt(III) bromide

In the title compound, [Co(CO(3))(C(10)H(9)N(3))(2)]Br, a distorted octa­hedral coordination of the Co(III) atom is completed by four N atoms of the two chelating di-2-pyridyl­amine ligands and two O atoms of the chelating carbonate anion. The di-2-pyridyl­amine ligands are nonplanar and the dihedra...

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Detalles Bibliográficos
Autores principales: Czapik, Agnieszka, Papadopoulos, Christos, Lalia-Kantouri, Maria, Gdaniec, Maria
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100002/
https://www.ncbi.nlm.nih.gov/pubmed/21753946
http://dx.doi.org/10.1107/S1600536811008051
Descripción
Sumario:In the title compound, [Co(CO(3))(C(10)H(9)N(3))(2)]Br, a distorted octa­hedral coordination of the Co(III) atom is completed by four N atoms of the two chelating di-2-pyridyl­amine ligands and two O atoms of the chelating carbonate anion. The di-2-pyridyl­amine ligands are nonplanar and the dihedral angles between the 2-pyridyl groups are 29.11 (9) and 37.15 (12)°. The coordination cation, which has approximate C (2) symmetry, is connected to the bromide ion via an N—H⋯Br(−) hydrogen bond. The ionic pair thus formed is further assembled into a dimer via N—H⋯O inter­actions about an inversion centre. A set of weaker C—H⋯O and C—H⋯Br(−) inter­actions connect the dimers into a three-dimensional network.