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(Carbonato-κ(2) O,O′)bis(di-2-pyridylamine-κ(2) N,N′)cobalt(III) bromide
In the title compound, [Co(CO(3))(C(10)H(9)N(3))(2)]Br, a distorted octahedral coordination of the Co(III) atom is completed by four N atoms of the two chelating di-2-pyridylamine ligands and two O atoms of the chelating carbonate anion. The di-2-pyridylamine ligands are nonplanar and the dihedra...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100002/ https://www.ncbi.nlm.nih.gov/pubmed/21753946 http://dx.doi.org/10.1107/S1600536811008051 |
| _version_ | 1782204136053276672 |
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| author | Czapik, Agnieszka Papadopoulos, Christos Lalia-Kantouri, Maria Gdaniec, Maria |
| author_facet | Czapik, Agnieszka Papadopoulos, Christos Lalia-Kantouri, Maria Gdaniec, Maria |
| author_sort | Czapik, Agnieszka |
| collection | PubMed |
| description | In the title compound, [Co(CO(3))(C(10)H(9)N(3))(2)]Br, a distorted octahedral coordination of the Co(III) atom is completed by four N atoms of the two chelating di-2-pyridylamine ligands and two O atoms of the chelating carbonate anion. The di-2-pyridylamine ligands are nonplanar and the dihedral angles between the 2-pyridyl groups are 29.11 (9) and 37.15 (12)°. The coordination cation, which has approximate C (2) symmetry, is connected to the bromide ion via an N—H⋯Br(−) hydrogen bond. The ionic pair thus formed is further assembled into a dimer via N—H⋯O interactions about an inversion centre. A set of weaker C—H⋯O and C—H⋯Br(−) interactions connect the dimers into a three-dimensional network. |
| format | Text |
| id | pubmed-3100002 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31000022011-07-13 (Carbonato-κ(2) O,O′)bis(di-2-pyridylamine-κ(2) N,N′)cobalt(III) bromide Czapik, Agnieszka Papadopoulos, Christos Lalia-Kantouri, Maria Gdaniec, Maria Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(CO(3))(C(10)H(9)N(3))(2)]Br, a distorted octahedral coordination of the Co(III) atom is completed by four N atoms of the two chelating di-2-pyridylamine ligands and two O atoms of the chelating carbonate anion. The di-2-pyridylamine ligands are nonplanar and the dihedral angles between the 2-pyridyl groups are 29.11 (9) and 37.15 (12)°. The coordination cation, which has approximate C (2) symmetry, is connected to the bromide ion via an N—H⋯Br(−) hydrogen bond. The ionic pair thus formed is further assembled into a dimer via N—H⋯O interactions about an inversion centre. A set of weaker C—H⋯O and C—H⋯Br(−) interactions connect the dimers into a three-dimensional network. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3100002/ /pubmed/21753946 http://dx.doi.org/10.1107/S1600536811008051 Text en © Czapik et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Czapik, Agnieszka Papadopoulos, Christos Lalia-Kantouri, Maria Gdaniec, Maria (Carbonato-κ(2) O,O′)bis(di-2-pyridylamine-κ(2) N,N′)cobalt(III) bromide |
| title | (Carbonato-κ(2)
O,O′)bis(di-2-pyridylamine-κ(2)
N,N′)cobalt(III) bromide |
| title_full | (Carbonato-κ(2)
O,O′)bis(di-2-pyridylamine-κ(2)
N,N′)cobalt(III) bromide |
| title_fullStr | (Carbonato-κ(2)
O,O′)bis(di-2-pyridylamine-κ(2)
N,N′)cobalt(III) bromide |
| title_full_unstemmed | (Carbonato-κ(2)
O,O′)bis(di-2-pyridylamine-κ(2)
N,N′)cobalt(III) bromide |
| title_short | (Carbonato-κ(2)
O,O′)bis(di-2-pyridylamine-κ(2)
N,N′)cobalt(III) bromide |
| title_sort | (carbonato-κ(2)
o,o′)bis(di-2-pyridylamine-κ(2)
n,n′)cobalt(iii) bromide |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100002/ https://www.ncbi.nlm.nih.gov/pubmed/21753946 http://dx.doi.org/10.1107/S1600536811008051 |
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