Bis(1,10-phenanthroline-κ(2) N,N′)[2-(4-sulfonato­anilino)acetato-κO]copper(II) dihydrate

In the title compound, [Cu(C(8)H(7)NO(5)S)(C(12)H(8)N(2))(2)]·2H(2)O, the Cu(II) ion is coordinated by four N atoms from two 1,10-phenanthroline (phen) ligands and one O atom from a 2-(4-sulfonato­anilino)acetate (spia) ligand in a distorted square-pyramidal geometry. Inter­molecular N—H⋯O and O—H⋯O...

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Detalles Bibliográficos
Autores principales: Lu, Yue, Li, Xing, Bing, Yue, Zha, Mei-Qin, Li, Yin-Xin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100003/
https://www.ncbi.nlm.nih.gov/pubmed/21753937
http://dx.doi.org/10.1107/S160053681100746X
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author Lu, Yue
Li, Xing
Bing, Yue
Zha, Mei-Qin
Li, Yin-Xin
author_facet Lu, Yue
Li, Xing
Bing, Yue
Zha, Mei-Qin
Li, Yin-Xin
author_sort Lu, Yue
collection PubMed
description In the title compound, [Cu(C(8)H(7)NO(5)S)(C(12)H(8)N(2))(2)]·2H(2)O, the Cu(II) ion is coordinated by four N atoms from two 1,10-phenanthroline (phen) ligands and one O atom from a 2-(4-sulfonato­anilino)acetate (spia) ligand in a distorted square-pyramidal geometry. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, as well as π–π inter­actions between phen ligands and between phen and spia ligands [centroid–centroid distances = 3.663 (3), 3.768 (3) and 3.565 (3) Å], result in a three-dimensional supra­molecular structure.
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spelling pubmed-31000032011-07-13 Bis(1,10-phenanthroline-κ(2) N,N′)[2-(4-sulfonato­anilino)acetato-κO]copper(II) dihydrate Lu, Yue Li, Xing Bing, Yue Zha, Mei-Qin Li, Yin-Xin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(7)NO(5)S)(C(12)H(8)N(2))(2)]·2H(2)O, the Cu(II) ion is coordinated by four N atoms from two 1,10-phenanthroline (phen) ligands and one O atom from a 2-(4-sulfonato­anilino)acetate (spia) ligand in a distorted square-pyramidal geometry. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, as well as π–π inter­actions between phen ligands and between phen and spia ligands [centroid–centroid distances = 3.663 (3), 3.768 (3) and 3.565 (3) Å], result in a three-dimensional supra­molecular structure. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3100003/ /pubmed/21753937 http://dx.doi.org/10.1107/S160053681100746X Text en © Lu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lu, Yue
Li, Xing
Bing, Yue
Zha, Mei-Qin
Li, Yin-Xin
Bis(1,10-phenanthroline-κ(2) N,N′)[2-(4-sulfonato­anilino)acetato-κO]copper(II) dihydrate
title Bis(1,10-phenanthroline-κ(2) N,N′)[2-(4-sulfonato­anilino)acetato-κO]copper(II) dihydrate
title_full Bis(1,10-phenanthroline-κ(2) N,N′)[2-(4-sulfonato­anilino)acetato-κO]copper(II) dihydrate
title_fullStr Bis(1,10-phenanthroline-κ(2) N,N′)[2-(4-sulfonato­anilino)acetato-κO]copper(II) dihydrate
title_full_unstemmed Bis(1,10-phenanthroline-κ(2) N,N′)[2-(4-sulfonato­anilino)acetato-κO]copper(II) dihydrate
title_short Bis(1,10-phenanthroline-κ(2) N,N′)[2-(4-sulfonato­anilino)acetato-κO]copper(II) dihydrate
title_sort bis(1,10-phenanthroline-κ(2) n,n′)[2-(4-sulfonato­anilino)acetato-κo]copper(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100003/
https://www.ncbi.nlm.nih.gov/pubmed/21753937
http://dx.doi.org/10.1107/S160053681100746X
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AT liyinxin bis110phenanthrolinek2nn24sulfonatoanilinoacetatokocopperiidihydrate

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