Tris(tetra­butyl­ammonium) tris­(nitrato-κ(2) O,O′)tetra­kis­(thio­cyanato-κN)thorium(IV)

The title compound, (C(16)H(36)N)(3)[Th(NCS)(4)(NO(3))(3)], was obtained from the reaction of Th(NO(3))(4)·5H(2)O with (Bu(4)N)(NCS). The Th(IV) atom is in a ten-coordinate environment of irregular geometry, being bound to the N atoms of the four thio­cyanate ions and to three bidentate nitrate ions...

Descripción completa

Detalles Bibliográficos
Autores principales: Lozano-Rodriguez, M. Janeth, Thuéry, Pierre, Petit, Sébastien, Copping, Roy, Mustre de Leon, Jose, Den Auwer, Christophe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100005/
https://www.ncbi.nlm.nih.gov/pubmed/21753998
http://dx.doi.org/10.1107/S1600536811009792
Descripción
Sumario:The title compound, (C(16)H(36)N)(3)[Th(NCS)(4)(NO(3))(3)], was obtained from the reaction of Th(NO(3))(4)·5H(2)O with (Bu(4)N)(NCS). The Th(IV) atom is in a ten-coordinate environment of irregular geometry, being bound to the N atoms of the four thio­cyanate ions and to three bidentate nitrate ions. The average Th—N and Th—O bond lengths are 2.481 (10) and 2.57 (3) Å, respectively.

Ejemplares similares