Tris(tetra­butyl­ammonium) tris­(nitrato-κ(2) O,O′)tetra­kis­(thio­cyanato-κN)thorium(IV)

The title compound, (C(16)H(36)N)(3)[Th(NCS)(4)(NO(3))(3)], was obtained from the reaction of Th(NO(3))(4)·5H(2)O with (Bu(4)N)(NCS). The Th(IV) atom is in a ten-coordinate environment of irregular geometry, being bound to the N atoms of the four thio­cyanate ions and to three bidentate nitrate ions...

Descripción completa

Detalles Bibliográficos
Autores principales: Lozano-Rodriguez, M. Janeth, Thuéry, Pierre, Petit, Sébastien, Copping, Roy, Mustre de Leon, Jose, Den Auwer, Christophe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100005/
https://www.ncbi.nlm.nih.gov/pubmed/21753998
http://dx.doi.org/10.1107/S1600536811009792
_version_ 1782204136783085568
author Lozano-Rodriguez, M. Janeth
Thuéry, Pierre
Petit, Sébastien
Copping, Roy
Mustre de Leon, Jose
Den Auwer, Christophe
author_facet Lozano-Rodriguez, M. Janeth
Thuéry, Pierre
Petit, Sébastien
Copping, Roy
Mustre de Leon, Jose
Den Auwer, Christophe
author_sort Lozano-Rodriguez, M. Janeth
collection PubMed
description The title compound, (C(16)H(36)N)(3)[Th(NCS)(4)(NO(3))(3)], was obtained from the reaction of Th(NO(3))(4)·5H(2)O with (Bu(4)N)(NCS). The Th(IV) atom is in a ten-coordinate environment of irregular geometry, being bound to the N atoms of the four thio­cyanate ions and to three bidentate nitrate ions. The average Th—N and Th—O bond lengths are 2.481 (10) and 2.57 (3) Å, respectively.
format Text
id pubmed-3100005
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31000052011-07-13 Tris(tetra­butyl­ammonium) tris­(nitrato-κ(2) O,O′)tetra­kis­(thio­cyanato-κN)thorium(IV) Lozano-Rodriguez, M. Janeth Thuéry, Pierre Petit, Sébastien Copping, Roy Mustre de Leon, Jose Den Auwer, Christophe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(16)H(36)N)(3)[Th(NCS)(4)(NO(3))(3)], was obtained from the reaction of Th(NO(3))(4)·5H(2)O with (Bu(4)N)(NCS). The Th(IV) atom is in a ten-coordinate environment of irregular geometry, being bound to the N atoms of the four thio­cyanate ions and to three bidentate nitrate ions. The average Th—N and Th—O bond lengths are 2.481 (10) and 2.57 (3) Å, respectively. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3100005/ /pubmed/21753998 http://dx.doi.org/10.1107/S1600536811009792 Text en © Lozano-Rodriguez et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lozano-Rodriguez, M. Janeth
Thuéry, Pierre
Petit, Sébastien
Copping, Roy
Mustre de Leon, Jose
Den Auwer, Christophe
Tris(tetra­butyl­ammonium) tris­(nitrato-κ(2) O,O′)tetra­kis­(thio­cyanato-κN)thorium(IV)
title Tris(tetra­butyl­ammonium) tris­(nitrato-κ(2) O,O′)tetra­kis­(thio­cyanato-κN)thorium(IV)
title_full Tris(tetra­butyl­ammonium) tris­(nitrato-κ(2) O,O′)tetra­kis­(thio­cyanato-κN)thorium(IV)
title_fullStr Tris(tetra­butyl­ammonium) tris­(nitrato-κ(2) O,O′)tetra­kis­(thio­cyanato-κN)thorium(IV)
title_full_unstemmed Tris(tetra­butyl­ammonium) tris­(nitrato-κ(2) O,O′)tetra­kis­(thio­cyanato-κN)thorium(IV)
title_short Tris(tetra­butyl­ammonium) tris­(nitrato-κ(2) O,O′)tetra­kis­(thio­cyanato-κN)thorium(IV)
title_sort tris(tetra­butyl­ammonium) tris­(nitrato-κ(2) o,o′)tetra­kis­(thio­cyanato-κn)thorium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100005/
https://www.ncbi.nlm.nih.gov/pubmed/21753998
http://dx.doi.org/10.1107/S1600536811009792
work_keys_str_mv AT lozanorodriguezmjaneth tristetrabutylammoniumtrisnitratok2ootetrakisthiocyanatoknthoriumiv
AT thuerypierre tristetrabutylammoniumtrisnitratok2ootetrakisthiocyanatoknthoriumiv
AT petitsebastien tristetrabutylammoniumtrisnitratok2ootetrakisthiocyanatoknthoriumiv
AT coppingroy tristetrabutylammoniumtrisnitratok2ootetrakisthiocyanatoknthoriumiv
AT mustredeleonjose tristetrabutylammoniumtrisnitratok2ootetrakisthiocyanatoknthoriumiv
AT denauwerchristophe tristetrabutylammoniumtrisnitratok2ootetrakisthiocyanatoknthoriumiv

Ejemplares similares