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(2,2′-Bipyridine-κ(2) N,N′)chlorido(2-hydroxy-2,2-diphenylacetato-κ(2) O (1),O (1′))copper(II)
The Cu(II) atom in the title complex, [Cu(C(14)H(11)O(3))Cl(C(10)H(8)N(2))], exists within a ClN(2)O(2) donor set defined by a chloride ion, an asymmetrically chelating carboxylate ligand, and a symmetrically chelating 2,2′-bipyridine molecule. The coordination geometry is square pyramidal with th...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100008/ https://www.ncbi.nlm.nih.gov/pubmed/21753935 http://dx.doi.org/10.1107/S160053681100729X |
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author | Reza, Md. Yeamin Banu, Laila Arjuman Islam, M. Saidul Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Reza, Md. Yeamin Banu, Laila Arjuman Islam, M. Saidul Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Reza, Md. Yeamin |
collection | PubMed |
description | The Cu(II) atom in the title complex, [Cu(C(14)H(11)O(3))Cl(C(10)H(8)N(2))], exists within a ClN(2)O(2) donor set defined by a chloride ion, an asymmetrically chelating carboxylate ligand, and a symmetrically chelating 2,2′-bipyridine molecule. The coordination geometry is square pyramidal with the axial site occupied by the O atom forming the weaker Cu—O interaction. The hydroxy group forms an intramolecular hydrogen bond with the axial O atom, as well as an intermolecular O—H⋯Cl hydrogen bond. The latter leads to the formation of [100] supramolecular chains in the crystal, with the Cu(II) atoms lying in a line. |
format | Text |
id | pubmed-3100008 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31000082011-07-13 (2,2′-Bipyridine-κ(2) N,N′)chlorido(2-hydroxy-2,2-diphenylacetato-κ(2) O (1),O (1′))copper(II) Reza, Md. Yeamin Banu, Laila Arjuman Islam, M. Saidul Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title complex, [Cu(C(14)H(11)O(3))Cl(C(10)H(8)N(2))], exists within a ClN(2)O(2) donor set defined by a chloride ion, an asymmetrically chelating carboxylate ligand, and a symmetrically chelating 2,2′-bipyridine molecule. The coordination geometry is square pyramidal with the axial site occupied by the O atom forming the weaker Cu—O interaction. The hydroxy group forms an intramolecular hydrogen bond with the axial O atom, as well as an intermolecular O—H⋯Cl hydrogen bond. The latter leads to the formation of [100] supramolecular chains in the crystal, with the Cu(II) atoms lying in a line. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3100008/ /pubmed/21753935 http://dx.doi.org/10.1107/S160053681100729X Text en © Reza et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Reza, Md. Yeamin Banu, Laila Arjuman Islam, M. Saidul Ng, Seik Weng Tiekink, Edward R. T. (2,2′-Bipyridine-κ(2) N,N′)chlorido(2-hydroxy-2,2-diphenylacetato-κ(2) O (1),O (1′))copper(II) |
title | (2,2′-Bipyridine-κ(2)
N,N′)chlorido(2-hydroxy-2,2-diphenylacetato-κ(2)
O
(1),O
(1′))copper(II) |
title_full | (2,2′-Bipyridine-κ(2)
N,N′)chlorido(2-hydroxy-2,2-diphenylacetato-κ(2)
O
(1),O
(1′))copper(II) |
title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)chlorido(2-hydroxy-2,2-diphenylacetato-κ(2)
O
(1),O
(1′))copper(II) |
title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)chlorido(2-hydroxy-2,2-diphenylacetato-κ(2)
O
(1),O
(1′))copper(II) |
title_short | (2,2′-Bipyridine-κ(2)
N,N′)chlorido(2-hydroxy-2,2-diphenylacetato-κ(2)
O
(1),O
(1′))copper(II) |
title_sort | (2,2′-bipyridine-κ(2)
n,n′)chlorido(2-hydroxy-2,2-diphenylacetato-κ(2)
o
(1),o
(1′))copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100008/ https://www.ncbi.nlm.nih.gov/pubmed/21753935 http://dx.doi.org/10.1107/S160053681100729X |
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