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(2,2′-Bipyridine-κ(2) N,N′)chlorido(2-hy­droxy-2,2-diphenyl­acetato-κ(2) O (1),O (1′))copper(II)

The Cu(II) atom in the title complex, [Cu(C(14)H(11)O(3))Cl(C(10)H(8)N(2))], exists within a ClN(2)O(2) donor set defined by a chloride ion, an asymmetrically chelating carboxyl­ate ligand, and a symmetrically chelating 2,2′-bipyridine mol­ecule. The coordination geometry is square pyramidal with th...

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Autores principales: Reza, Md. Yeamin, Banu, Laila Arjuman, Islam, M. Saidul, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100008/
https://www.ncbi.nlm.nih.gov/pubmed/21753935
http://dx.doi.org/10.1107/S160053681100729X
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author Reza, Md. Yeamin
Banu, Laila Arjuman
Islam, M. Saidul
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Reza, Md. Yeamin
Banu, Laila Arjuman
Islam, M. Saidul
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Reza, Md. Yeamin
collection PubMed
description The Cu(II) atom in the title complex, [Cu(C(14)H(11)O(3))Cl(C(10)H(8)N(2))], exists within a ClN(2)O(2) donor set defined by a chloride ion, an asymmetrically chelating carboxyl­ate ligand, and a symmetrically chelating 2,2′-bipyridine mol­ecule. The coordination geometry is square pyramidal with the axial site occupied by the O atom forming the weaker Cu—O inter­action. The hy­droxy group forms an intra­molecular hydrogen bond with the axial O atom, as well as an inter­molecular O—H⋯Cl hydrogen bond. The latter leads to the formation of [100] supra­molecular chains in the crystal, with the Cu(II) atoms lying in a line.
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spelling pubmed-31000082011-07-13 (2,2′-Bipyridine-κ(2) N,N′)chlorido(2-hy­droxy-2,2-diphenyl­acetato-κ(2) O (1),O (1′))copper(II) Reza, Md. Yeamin Banu, Laila Arjuman Islam, M. Saidul Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title complex, [Cu(C(14)H(11)O(3))Cl(C(10)H(8)N(2))], exists within a ClN(2)O(2) donor set defined by a chloride ion, an asymmetrically chelating carboxyl­ate ligand, and a symmetrically chelating 2,2′-bipyridine mol­ecule. The coordination geometry is square pyramidal with the axial site occupied by the O atom forming the weaker Cu—O inter­action. The hy­droxy group forms an intra­molecular hydrogen bond with the axial O atom, as well as an inter­molecular O—H⋯Cl hydrogen bond. The latter leads to the formation of [100] supra­molecular chains in the crystal, with the Cu(II) atoms lying in a line. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3100008/ /pubmed/21753935 http://dx.doi.org/10.1107/S160053681100729X Text en © Reza et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reza, Md. Yeamin
Banu, Laila Arjuman
Islam, M. Saidul
Ng, Seik Weng
Tiekink, Edward R. T.
(2,2′-Bipyridine-κ(2) N,N′)chlorido(2-hy­droxy-2,2-diphenyl­acetato-κ(2) O (1),O (1′))copper(II)
title (2,2′-Bipyridine-κ(2) N,N′)chlorido(2-hy­droxy-2,2-diphenyl­acetato-κ(2) O (1),O (1′))copper(II)
title_full (2,2′-Bipyridine-κ(2) N,N′)chlorido(2-hy­droxy-2,2-diphenyl­acetato-κ(2) O (1),O (1′))copper(II)
title_fullStr (2,2′-Bipyridine-κ(2) N,N′)chlorido(2-hy­droxy-2,2-diphenyl­acetato-κ(2) O (1),O (1′))copper(II)
title_full_unstemmed (2,2′-Bipyridine-κ(2) N,N′)chlorido(2-hy­droxy-2,2-diphenyl­acetato-κ(2) O (1),O (1′))copper(II)
title_short (2,2′-Bipyridine-κ(2) N,N′)chlorido(2-hy­droxy-2,2-diphenyl­acetato-κ(2) O (1),O (1′))copper(II)
title_sort (2,2′-bipyridine-κ(2) n,n′)chlorido(2-hy­droxy-2,2-diphenyl­acetato-κ(2) o (1),o (1′))copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100008/
https://www.ncbi.nlm.nih.gov/pubmed/21753935
http://dx.doi.org/10.1107/S160053681100729X
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