Di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide-κO)tin(II)]

The structure of the title compound, [Sn(2)Cl(4)(C(2)H(6)OS)(4)], contains dimers formed through weak Sn⋯Cl [3.691 (2) Å] inter­actions, resulting in a planar Sn(2)Cl(2) core with an inversion center at the centre of the four-membered ring. The Sn(II) atoms are penta­coordinated and have a distorted...

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Detalles Bibliográficos
Autores principales: Barbul, Ioana, Varga, Richard A., Silvestru, Cristian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100018/
https://www.ncbi.nlm.nih.gov/pubmed/21753997
http://dx.doi.org/10.1107/S1600536811009895
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author Barbul, Ioana
Varga, Richard A.
Silvestru, Cristian
author_facet Barbul, Ioana
Varga, Richard A.
Silvestru, Cristian
author_sort Barbul, Ioana
collection PubMed
description The structure of the title compound, [Sn(2)Cl(4)(C(2)H(6)OS)(4)], contains dimers formed through weak Sn⋯Cl [3.691 (2) Å] inter­actions, resulting in a planar Sn(2)Cl(2) core with an inversion center at the centre of the four-membered ring. The Sn(II) atoms are penta­coordinated and have a distorted octa­hedral Ψ-SnCl(3)O(2) coordination geometry. The O atoms from the dimethyl sulfoxide mol­ecules occupy trans positions, while the Cl atoms exhibit a meridional arrangement.
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spelling pubmed-31000182011-07-13 Di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide-κO)tin(II)] Barbul, Ioana Varga, Richard A. Silvestru, Cristian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Sn(2)Cl(4)(C(2)H(6)OS)(4)], contains dimers formed through weak Sn⋯Cl [3.691 (2) Å] inter­actions, resulting in a planar Sn(2)Cl(2) core with an inversion center at the centre of the four-membered ring. The Sn(II) atoms are penta­coordinated and have a distorted octa­hedral Ψ-SnCl(3)O(2) coordination geometry. The O atoms from the dimethyl sulfoxide mol­ecules occupy trans positions, while the Cl atoms exhibit a meridional arrangement. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3100018/ /pubmed/21753997 http://dx.doi.org/10.1107/S1600536811009895 Text en © Barbul et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Barbul, Ioana
Varga, Richard A.
Silvestru, Cristian
Di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide-κO)tin(II)]
title Di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide-κO)tin(II)]
title_full Di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide-κO)tin(II)]
title_fullStr Di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide-κO)tin(II)]
title_full_unstemmed Di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide-κO)tin(II)]
title_short Di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide-κO)tin(II)]
title_sort di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide-κo)tin(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100018/
https://www.ncbi.nlm.nih.gov/pubmed/21753997
http://dx.doi.org/10.1107/S1600536811009895
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AT vargaricharda dimchloridobischloridobisdimethylsulfoxidekotinii
AT silvestrucristian dimchloridobischloridobisdimethylsulfoxidekotinii

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