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{2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ(3) P,C (1),P′}iodidonickel(II)
In the title complex, [Ni(C(30)H(23)O(2)P(2))I], the divalent Ni atom is coordinated by two P atoms and one C atom from the 1,3-bis[(diphenylphosphanyl)oxy]benzene ligand; the distorted square-planar geometry is completed by an iodide ligand. The largest distortions from ideal square-planar geom...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100022/ https://www.ncbi.nlm.nih.gov/pubmed/21753960 http://dx.doi.org/10.1107/S1600536811008828 |
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author | Salah, Abderrahmen Zargarian, Davit |
author_facet | Salah, Abderrahmen Zargarian, Davit |
author_sort | Salah, Abderrahmen |
collection | PubMed |
description | In the title complex, [Ni(C(30)H(23)O(2)P(2))I], the divalent Ni atom is coordinated by two P atoms and one C atom from the 1,3-bis[(diphenylphosphanyl)oxy]benzene ligand; the distorted square-planar geometry is completed by an iodide ligand. The largest distortions from ideal square-planar geometry are reflected in the P—Ni—P angle of 164.20 (2)° and the P—Ni—C angles of 82.09 (6) and 82.11 (6)°. The rather short Ni—C bond length [1.890 (2) Å] is anticipated in light of the much stronger trans influence of the aryl moiety compared to the iodide ligand. The P-bound phenyl rings adopt different orientations to minimize steric repulsion among themselves. |
format | Text |
id | pubmed-3100022 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31000222011-07-13 {2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ(3) P,C (1),P′}iodidonickel(II) Salah, Abderrahmen Zargarian, Davit Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(30)H(23)O(2)P(2))I], the divalent Ni atom is coordinated by two P atoms and one C atom from the 1,3-bis[(diphenylphosphanyl)oxy]benzene ligand; the distorted square-planar geometry is completed by an iodide ligand. The largest distortions from ideal square-planar geometry are reflected in the P—Ni—P angle of 164.20 (2)° and the P—Ni—C angles of 82.09 (6) and 82.11 (6)°. The rather short Ni—C bond length [1.890 (2) Å] is anticipated in light of the much stronger trans influence of the aryl moiety compared to the iodide ligand. The P-bound phenyl rings adopt different orientations to minimize steric repulsion among themselves. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3100022/ /pubmed/21753960 http://dx.doi.org/10.1107/S1600536811008828 Text en © Zargarian and Salah 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Salah, Abderrahmen Zargarian, Davit {2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ(3) P,C (1),P′}iodidonickel(II) |
title | {2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ(3)
P,C
(1),P′}iodidonickel(II) |
title_full | {2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ(3)
P,C
(1),P′}iodidonickel(II) |
title_fullStr | {2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ(3)
P,C
(1),P′}iodidonickel(II) |
title_full_unstemmed | {2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ(3)
P,C
(1),P′}iodidonickel(II) |
title_short | {2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ(3)
P,C
(1),P′}iodidonickel(II) |
title_sort | {2,6-bis[(diphenylphosphanyl)oxy]phenyl-κ(3)
p,c
(1),p′}iodidonickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100022/ https://www.ncbi.nlm.nih.gov/pubmed/21753960 http://dx.doi.org/10.1107/S1600536811008828 |
work_keys_str_mv | AT salahabderrahmen 26bisdiphenylphosphanyloxyphenylk3pc1piodidonickelii AT zargariandavit 26bisdiphenylphosphanyloxyphenylk3pc1piodidonickelii |