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{2,6-Bis[(diphenyl­phosphan­yl)­oxy]phen­yl-κ(3) P,C (1),P′}iodidonickel(II)

In the title complex, [Ni(C(30)H(23)O(2)P(2))I], the divalent Ni atom is coordinated by two P atoms and one C atom from the 1,3-bis­[(diphenyl­phosphan­yl)­oxy]benzene ligand; the distorted square-planar geometry is completed by an iodide ligand. The largest distortions from ideal square-planar geom...

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Detalles Bibliográficos
Autores principales: Salah, Abderrahmen, Zargarian, Davit
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100022/
https://www.ncbi.nlm.nih.gov/pubmed/21753960
http://dx.doi.org/10.1107/S1600536811008828
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author Salah, Abderrahmen
Zargarian, Davit
author_facet Salah, Abderrahmen
Zargarian, Davit
author_sort Salah, Abderrahmen
collection PubMed
description In the title complex, [Ni(C(30)H(23)O(2)P(2))I], the divalent Ni atom is coordinated by two P atoms and one C atom from the 1,3-bis­[(diphenyl­phosphan­yl)­oxy]benzene ligand; the distorted square-planar geometry is completed by an iodide ligand. The largest distortions from ideal square-planar geometry are reflected in the P—Ni—P angle of 164.20 (2)° and the P—Ni—C angles of 82.09 (6) and 82.11 (6)°. The rather short Ni—C bond length [1.890 (2) Å] is anti­cipated in light of the much stronger trans influence of the aryl moiety compared to the iodide ligand. The P-bound phenyl rings adopt different orientations to minimize steric repulsion among themselves.
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spelling pubmed-31000222011-07-13 {2,6-Bis[(diphenyl­phosphan­yl)­oxy]phen­yl-κ(3) P,C (1),P′}iodidonickel(II) Salah, Abderrahmen Zargarian, Davit Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(30)H(23)O(2)P(2))I], the divalent Ni atom is coordinated by two P atoms and one C atom from the 1,3-bis­[(diphenyl­phosphan­yl)­oxy]benzene ligand; the distorted square-planar geometry is completed by an iodide ligand. The largest distortions from ideal square-planar geometry are reflected in the P—Ni—P angle of 164.20 (2)° and the P—Ni—C angles of 82.09 (6) and 82.11 (6)°. The rather short Ni—C bond length [1.890 (2) Å] is anti­cipated in light of the much stronger trans influence of the aryl moiety compared to the iodide ligand. The P-bound phenyl rings adopt different orientations to minimize steric repulsion among themselves. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3100022/ /pubmed/21753960 http://dx.doi.org/10.1107/S1600536811008828 Text en © Zargarian and Salah 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Salah, Abderrahmen
Zargarian, Davit
{2,6-Bis[(diphenyl­phosphan­yl)­oxy]phen­yl-κ(3) P,C (1),P′}iodidonickel(II)
title {2,6-Bis[(diphenyl­phosphan­yl)­oxy]phen­yl-κ(3) P,C (1),P′}iodidonickel(II)
title_full {2,6-Bis[(diphenyl­phosphan­yl)­oxy]phen­yl-κ(3) P,C (1),P′}iodidonickel(II)
title_fullStr {2,6-Bis[(diphenyl­phosphan­yl)­oxy]phen­yl-κ(3) P,C (1),P′}iodidonickel(II)
title_full_unstemmed {2,6-Bis[(diphenyl­phosphan­yl)­oxy]phen­yl-κ(3) P,C (1),P′}iodidonickel(II)
title_short {2,6-Bis[(diphenyl­phosphan­yl)­oxy]phen­yl-κ(3) P,C (1),P′}iodidonickel(II)
title_sort {2,6-bis[(diphenyl­phosphan­yl)­oxy]phen­yl-κ(3) p,c (1),p′}iodidonickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100022/
https://www.ncbi.nlm.nih.gov/pubmed/21753960
http://dx.doi.org/10.1107/S1600536811008828
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