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Methyl 9-diethyl­amino-2,2-bis­(4-meth­oxy­phen­yl)-2H-benzo[h]chromene-5-carboxyl­ate

In the title compound, C(31)H(29)NO(5), the methyl carboxyl­ate and dimethyl­amino groups on the naphtho­pyran group are almost coplanar with the naphtho­pyran ring system [r.m.s. deviations = 0.08 (2) and 0.161 (2) Å, respectively]. The dihedral angle between the methyl carboxyl­ate and dimethyl­am...

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Detalles Bibliográficos
Autores principales: Kim, Moon-Hwan, Park, Hee-Moon, Kim, Chong-Hyeak
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100025/
https://www.ncbi.nlm.nih.gov/pubmed/21754239
http://dx.doi.org/10.1107/S160053681101049X
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author Kim, Moon-Hwan
Park, Hee-Moon
Kim, Chong-Hyeak
author_facet Kim, Moon-Hwan
Park, Hee-Moon
Kim, Chong-Hyeak
author_sort Kim, Moon-Hwan
collection PubMed
description In the title compound, C(31)H(29)NO(5), the methyl carboxyl­ate and dimethyl­amino groups on the naphtho­pyran group are almost coplanar with the naphtho­pyran ring system [r.m.s. deviations = 0.08 (2) and 0.161 (2) Å, respectively]. The dihedral angle between the methyl carboxyl­ate and dimethyl­amino groups is 4.9 (1)°. The pyran ring has an envelope conformation with the quaternary C atom out of plane by 0.4739 (13) Å. The meth­oxy­phenyl substituent forms a dihedral angle of 16.6 (1)° with the plane of the benzene ring, while the other meth­oxy­phenyl group is almost coplanar, making a dihedral angle of 1.4 (1)°.
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spelling pubmed-31000252011-07-13 Methyl 9-diethyl­amino-2,2-bis­(4-meth­oxy­phen­yl)-2H-benzo[h]chromene-5-carboxyl­ate Kim, Moon-Hwan Park, Hee-Moon Kim, Chong-Hyeak Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(31)H(29)NO(5), the methyl carboxyl­ate and dimethyl­amino groups on the naphtho­pyran group are almost coplanar with the naphtho­pyran ring system [r.m.s. deviations = 0.08 (2) and 0.161 (2) Å, respectively]. The dihedral angle between the methyl carboxyl­ate and dimethyl­amino groups is 4.9 (1)°. The pyran ring has an envelope conformation with the quaternary C atom out of plane by 0.4739 (13) Å. The meth­oxy­phenyl substituent forms a dihedral angle of 16.6 (1)° with the plane of the benzene ring, while the other meth­oxy­phenyl group is almost coplanar, making a dihedral angle of 1.4 (1)°. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3100025/ /pubmed/21754239 http://dx.doi.org/10.1107/S160053681101049X Text en © Kim et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kim, Moon-Hwan
Park, Hee-Moon
Kim, Chong-Hyeak
Methyl 9-diethyl­amino-2,2-bis­(4-meth­oxy­phen­yl)-2H-benzo[h]chromene-5-carboxyl­ate
title Methyl 9-diethyl­amino-2,2-bis­(4-meth­oxy­phen­yl)-2H-benzo[h]chromene-5-carboxyl­ate
title_full Methyl 9-diethyl­amino-2,2-bis­(4-meth­oxy­phen­yl)-2H-benzo[h]chromene-5-carboxyl­ate
title_fullStr Methyl 9-diethyl­amino-2,2-bis­(4-meth­oxy­phen­yl)-2H-benzo[h]chromene-5-carboxyl­ate
title_full_unstemmed Methyl 9-diethyl­amino-2,2-bis­(4-meth­oxy­phen­yl)-2H-benzo[h]chromene-5-carboxyl­ate
title_short Methyl 9-diethyl­amino-2,2-bis­(4-meth­oxy­phen­yl)-2H-benzo[h]chromene-5-carboxyl­ate
title_sort methyl 9-diethyl­amino-2,2-bis­(4-meth­oxy­phen­yl)-2h-benzo[h]chromene-5-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100025/
https://www.ncbi.nlm.nih.gov/pubmed/21754239
http://dx.doi.org/10.1107/S160053681101049X
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