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Methyl 9-diethylamino-2,2-bis(4-methoxyphenyl)-2H-benzo[h]chromene-5-carboxylate
In the title compound, C(31)H(29)NO(5), the methyl carboxylate and dimethylamino groups on the naphthopyran group are almost coplanar with the naphthopyran ring system [r.m.s. deviations = 0.08 (2) and 0.161 (2) Å, respectively]. The dihedral angle between the methyl carboxylate and dimethylam...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100025/ https://www.ncbi.nlm.nih.gov/pubmed/21754239 http://dx.doi.org/10.1107/S160053681101049X |
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author | Kim, Moon-Hwan Park, Hee-Moon Kim, Chong-Hyeak |
author_facet | Kim, Moon-Hwan Park, Hee-Moon Kim, Chong-Hyeak |
author_sort | Kim, Moon-Hwan |
collection | PubMed |
description | In the title compound, C(31)H(29)NO(5), the methyl carboxylate and dimethylamino groups on the naphthopyran group are almost coplanar with the naphthopyran ring system [r.m.s. deviations = 0.08 (2) and 0.161 (2) Å, respectively]. The dihedral angle between the methyl carboxylate and dimethylamino groups is 4.9 (1)°. The pyran ring has an envelope conformation with the quaternary C atom out of plane by 0.4739 (13) Å. The methoxyphenyl substituent forms a dihedral angle of 16.6 (1)° with the plane of the benzene ring, while the other methoxyphenyl group is almost coplanar, making a dihedral angle of 1.4 (1)°. |
format | Text |
id | pubmed-3100025 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31000252011-07-13 Methyl 9-diethylamino-2,2-bis(4-methoxyphenyl)-2H-benzo[h]chromene-5-carboxylate Kim, Moon-Hwan Park, Hee-Moon Kim, Chong-Hyeak Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(31)H(29)NO(5), the methyl carboxylate and dimethylamino groups on the naphthopyran group are almost coplanar with the naphthopyran ring system [r.m.s. deviations = 0.08 (2) and 0.161 (2) Å, respectively]. The dihedral angle between the methyl carboxylate and dimethylamino groups is 4.9 (1)°. The pyran ring has an envelope conformation with the quaternary C atom out of plane by 0.4739 (13) Å. The methoxyphenyl substituent forms a dihedral angle of 16.6 (1)° with the plane of the benzene ring, while the other methoxyphenyl group is almost coplanar, making a dihedral angle of 1.4 (1)°. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3100025/ /pubmed/21754239 http://dx.doi.org/10.1107/S160053681101049X Text en © Kim et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kim, Moon-Hwan Park, Hee-Moon Kim, Chong-Hyeak Methyl 9-diethylamino-2,2-bis(4-methoxyphenyl)-2H-benzo[h]chromene-5-carboxylate |
title | Methyl 9-diethylamino-2,2-bis(4-methoxyphenyl)-2H-benzo[h]chromene-5-carboxylate |
title_full | Methyl 9-diethylamino-2,2-bis(4-methoxyphenyl)-2H-benzo[h]chromene-5-carboxylate |
title_fullStr | Methyl 9-diethylamino-2,2-bis(4-methoxyphenyl)-2H-benzo[h]chromene-5-carboxylate |
title_full_unstemmed | Methyl 9-diethylamino-2,2-bis(4-methoxyphenyl)-2H-benzo[h]chromene-5-carboxylate |
title_short | Methyl 9-diethylamino-2,2-bis(4-methoxyphenyl)-2H-benzo[h]chromene-5-carboxylate |
title_sort | methyl 9-diethylamino-2,2-bis(4-methoxyphenyl)-2h-benzo[h]chromene-5-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100025/ https://www.ncbi.nlm.nih.gov/pubmed/21754239 http://dx.doi.org/10.1107/S160053681101049X |
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