cis-Bis{1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureato-κ(2) O,S}nickel(II)

In the title compound, [Ni(C(20)H(17)N(2)O(2)S)(2)], the Ni(II) atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureate ligands in a distorted square-planar geometry. The two O and two S atoms are mutually cis to each other. The Ni—S and Ni—O bond lengths li...

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Detalles Bibliográficos
Autores principales: Pérez, Hiram, da Silva, Cecilia C. P., Plutín, Ana M., de Simone, Carlos A., Ellena, Javier
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100031/
https://www.ncbi.nlm.nih.gov/pubmed/21754011
http://dx.doi.org/10.1107/S1600536811010749
Descripción
Sumario:In the title compound, [Ni(C(20)H(17)N(2)O(2)S)(2)], the Ni(II) atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureate ligands in a distorted square-planar geometry. The two O and two S atoms are mutually cis to each other. The Ni—S and Ni—O bond lengths lie within the range of those found in related structures. The dihedral angle between the planes of the two chelating rings is 20.33 (6)°.

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