cis-Bis{1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureato-κ(2) O,S}nickel(II)

In the title compound, [Ni(C(20)H(17)N(2)O(2)S)(2)], the Ni(II) atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureate ligands in a distorted square-planar geometry. The two O and two S atoms are mutually cis to each other. The Ni—S and Ni—O bond lengths li...

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Autores principales: Pérez, Hiram, da Silva, Cecilia C. P., Plutín, Ana M., de Simone, Carlos A., Ellena, Javier
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100031/
https://www.ncbi.nlm.nih.gov/pubmed/21754011
http://dx.doi.org/10.1107/S1600536811010749
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author Pérez, Hiram
da Silva, Cecilia C. P.
Plutín, Ana M.
de Simone, Carlos A.
Ellena, Javier
author_facet Pérez, Hiram
da Silva, Cecilia C. P.
Plutín, Ana M.
de Simone, Carlos A.
Ellena, Javier
author_sort Pérez, Hiram
collection PubMed
description In the title compound, [Ni(C(20)H(17)N(2)O(2)S)(2)], the Ni(II) atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureate ligands in a distorted square-planar geometry. The two O and two S atoms are mutually cis to each other. The Ni—S and Ni—O bond lengths lie within the range of those found in related structures. The dihedral angle between the planes of the two chelating rings is 20.33 (6)°.
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spelling pubmed-31000312011-07-13 cis-Bis{1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureato-κ(2) O,S}nickel(II) Pérez, Hiram da Silva, Cecilia C. P. Plutín, Ana M. de Simone, Carlos A. Ellena, Javier Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(20)H(17)N(2)O(2)S)(2)], the Ni(II) atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureate ligands in a distorted square-planar geometry. The two O and two S atoms are mutually cis to each other. The Ni—S and Ni—O bond lengths lie within the range of those found in related structures. The dihedral angle between the planes of the two chelating rings is 20.33 (6)°. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3100031/ /pubmed/21754011 http://dx.doi.org/10.1107/S1600536811010749 Text en © Pérez et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pérez, Hiram
da Silva, Cecilia C. P.
Plutín, Ana M.
de Simone, Carlos A.
Ellena, Javier
cis-Bis{1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureato-κ(2) O,S}nickel(II)
title cis-Bis{1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureato-κ(2) O,S}nickel(II)
title_full cis-Bis{1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureato-κ(2) O,S}nickel(II)
title_fullStr cis-Bis{1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureato-κ(2) O,S}nickel(II)
title_full_unstemmed cis-Bis{1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureato-κ(2) O,S}nickel(II)
title_short cis-Bis{1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureato-κ(2) O,S}nickel(II)
title_sort cis-bis{1,1-dibenzyl-3-[(furan-2-yl)carbon­yl]thio­ureato-κ(2) o,s}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100031/
https://www.ncbi.nlm.nih.gov/pubmed/21754011
http://dx.doi.org/10.1107/S1600536811010749
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